{"id":"W2319551214","doi":"10.1021/jp511021v","title":"Photoinduced Dynamics of Charge Separation: From Photosynthesis to Polymer–Fullerene Bulk Heterojunctions","year":2015,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry B","topic":"Organic Electronics and Photovoltaics","field":"Engineering","cited_by":57,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"Basic Energy Sciences; Deutsche Forschungsgemeinschaft","keywords":"Fullerene; Materials science; Organic solar cell; Chemical physics; Acceptor; Polymer; Electron paramagnetic resonance; Charge carrier; Polymer solar cell; Photoinduced charge separation; Heterojunction; Artificial photosynthesis; Singlet state; Photochemistry; Optoelectronics; Chemistry; Organic chemistry; Nuclear magnetic resonance; Photocatalysis; Atomic physics; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001229519,0.000128475,0.0002486137,0.00001644583,0.0000292863,0.00001200973,0.000253343,0.00005175241,0.0001083121],"category_scores_gemma":[0.00003077285,0.00009692352,0.0001059156,0.0001597436,0.00002245894,0.00005279607,0.00002609232,0.0002690983,0.00001409523],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001269382,"about_ca_system_score_gemma":0.00006842077,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003020182,"about_ca_topic_score_gemma":0.000006752032,"domain_scores_codex":[0.9992582,0.00001561313,0.0002593135,0.00006116524,0.0002520498,0.0001536554],"domain_scores_gemma":[0.9993303,0.00009199971,0.0001103845,0.0002157568,0.00009811744,0.0001534285],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004363685,0.00006156867,0.000004281959,0.00001104322,0.00009682121,9.073685e-7,0.0003904049,0.002436231,0.9960685,0.000008800876,0.0007394817,0.0001383334],"study_design_scores_gemma":[0.0002236124,0.0000787247,0.000006443408,0.00002388753,0.00006903094,0.0000123851,0.00007833369,0.02156054,0.9772363,0.0002513257,0.0003619325,0.00009747941],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9979302,0.0001771398,0.0004392093,0.0001491048,0.00009796659,0.00004463158,0.00004710642,0.00001806351,0.001096602],"genre_scores_gemma":[0.99935,0.00001815146,0.00002192645,0.00002237483,0.0004333154,0.000001590521,0.000006399409,0.00002277865,0.0001234385],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01912431,"threshold_uncertainty_score":0.3952426,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01127392727468349,"score_gpt":0.2276667180638777,"score_spread":0.2163927907891942,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}