{"id":"W2319756671","doi":"10.1021/jacs.5b00151","title":"Mechanochemical Ruthenium-Catalyzed Olefin Metathesis","year":2015,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":178,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Centre in Green Chemistry and Catalysis","funders":"Fonds de recherche du Québec – Nature et technologies; Natural Sciences and Engineering Research Council of Canada; Canada Foundation for Innovation","keywords":"Olefin metathesis; Chemistry; Metathesis; Ruthenium; Catalysis; Ring-opening metathesis polymerisation; Acyclic diene metathesis; Salt metathesis reaction; Ring-closing metathesis; Olefin fiber; Organic chemistry; Combinatorial chemistry; Polymerization","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001904326,0.0004417262,0.0002587736,0.0002482689,0.0001678501,0.0002673811,0.000510302,0.0003618709,0.00134263],"category_scores_gemma":[0.0002374118,0.0002134632,0.0003585223,0.0001554591,0.0002464337,0.000574738,0.0004465375,0.0006950695,0.00056504],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003288682,"about_ca_system_score_gemma":0.0002764864,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001881536,"about_ca_topic_score_gemma":0.0004689909,"domain_scores_codex":[0.9998111,0.00001594502,0.00001474986,0.00003799863,0.00006739758,0.00005283779],"domain_scores_gemma":[0.999933,0.0000144608,0.00002198908,0.00001770529,0.000007254564,0.000005632493],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002565081,0.00005889114,0.0001297274,0.0001353698,0.00001445439,0.0001676186,0.00001697249,0.0007106694,0.9835681,0.002918369,0.0001785773,0.01207563],"study_design_scores_gemma":[0.000009966606,0.0001464171,0.0002447216,0.000005728828,0.000008322036,0.0003831358,0.000004989777,0.001029129,0.9930806,0.000257782,0.004820885,0.000008347854],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7988524,0.01056547,0.1576181,0.001176222,0.0005722584,0.0003182525,0.000491851,0.002222562,0.02818291],"genre_scores_gemma":[0.9705894,0.002284466,0.02431815,0.0001034724,0.00004428164,0.00006071464,0.0001227779,0.00003641571,0.002440316],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00134263,"threshold_uncertainty_score":0.004491508,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02661023862757599,"score_gpt":0.2825303424550839,"score_spread":0.2559201038275079,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}