{"id":"W2319756671","doi":"10.1021/jacs.5b00151","title":"Mechanochemical Ruthenium-Catalyzed Olefin Metathesis","year":2015,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":178,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Centre in Green Chemistry and Catalysis","funders":"Fonds de recherche du Québec – Nature et technologies; Natural Sciences and Engineering Research Council of Canada; Canada Foundation for Innovation","keywords":"Olefin metathesis; Chemistry; Metathesis; Ruthenium; Catalysis; Ring-opening metathesis polymerisation; Acyclic diene metathesis; Salt metathesis reaction; Ring-closing metathesis; Olefin fiber; Organic chemistry; Combinatorial chemistry; Polymerization","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0009751153,0.0003038108,0.0007608255,0.00001311406,0.00005930821,0.00003956964,0.001419001,0.000158691,0.0002820331],"category_scores_gemma":[0.002100712,0.0002030541,0.001249363,0.0004364519,0.0006760622,0.00007751477,0.000383849,0.0008611714,0.0000131864],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005106467,"about_ca_system_score_gemma":0.0003161869,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001789258,"about_ca_topic_score_gemma":8.189772e-8,"domain_scores_codex":[0.9975349,0.00007454218,0.0007373576,0.0002831537,0.0009456534,0.0004243779],"domain_scores_gemma":[0.9967874,0.0005279759,0.00126212,0.0007153201,0.0002704785,0.000436747],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009279397,0.0001337619,0.0001890508,0.00002266437,0.0002692216,0.000003724529,0.0004551763,0.000001919605,0.9865252,0.000008692509,0.01005439,0.002243418],"study_design_scores_gemma":[0.0007487643,0.00001143805,0.000008598005,0.00004783925,0.0002693773,0.0003889391,0.001514811,0.00008635585,0.9897986,0.001228385,0.005654303,0.0002425825],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9941237,0.0002444715,0.0005062197,0.003471521,0.0001587757,0.00003023707,0.00001212886,0.00004414633,0.001408806],"genre_scores_gemma":[0.9556644,0.00003007163,0.0424831,0.0004813359,0.0008670505,0.000003933771,0.000001828924,0.00006192893,0.0004063552],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04197688,"threshold_uncertainty_score":0.8280305,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02661023862757599,"score_gpt":0.2825303424550839,"score_spread":0.2559201038275079,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}