{"id":"W2319851581","doi":"10.1021/op4003449","title":"Process Intensification of the Suzuki–Miyaura Reaction over Sol–Gel Entrapped Catalyst Silia<i>Cat</i> DPP-Pd Under Conditions of Continuous Flow","year":2014,"lang":"en","type":"article","venue":"Organic Process Research & Development","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":32,"is_retracted":false,"has_abstract":true,"ca_institutions":"SiliCycle (Canada)","funders":"Università degli Studi di Palermo","keywords":"Catalysis; Halide; Aryl; Chemistry; Process (computing); Continuous flow; Coupling reaction; Flow (mathematics); Combinatorial chemistry; Reaction conditions; Chemical engineering; Process engineering; Organic chemistry; Computer science; Mechanics; Biochemical engineering; Engineering; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001115686,0.0002841972,0.0004224941,0.0002227978,0.0005296439,0.00007928722,0.0008244661,0.0002307876,0.0004633316],"category_scores_gemma":[0.001640992,0.0002422089,0.0001036957,0.001051998,0.0006303503,0.000265236,0.000209714,0.0006163954,0.0000711082],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006313975,"about_ca_system_score_gemma":0.002077335,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001601721,"about_ca_topic_score_gemma":0.0002624446,"domain_scores_codex":[0.9963344,0.000009573313,0.0008916923,0.0006335929,0.001499209,0.0006315433],"domain_scores_gemma":[0.995715,0.0003641731,0.0004882139,0.0009250497,0.002338215,0.0001693328],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000647659,0.000436241,0.002577998,0.0007917368,0.0001275472,7.35099e-7,0.00301694,0.00004892972,0.9913625,0.0001287721,0.0004152155,0.001028593],"study_design_scores_gemma":[0.0006977345,0.00001844619,0.01275049,0.0003446557,0.00004722742,0.00002654626,0.003508461,0.0007166883,0.9802526,0.0008596717,0.000526479,0.0002510623],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9976423,0.00005043329,0.0002821128,0.0005428205,0.0001271254,0.0004330394,0.00005442467,0.00009471229,0.000773054],"genre_scores_gemma":[0.997992,0.0000336661,0.00004019803,0.00002974508,0.00007803894,0.0001894055,0.0003064889,0.00006481233,0.001265633],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01110999,"threshold_uncertainty_score":0.9876991,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02292426143349557,"score_gpt":0.3294071516201261,"score_spread":0.3064828901866305,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}