{"id":"W2319951293","doi":"10.1021/jp511500k","title":"Kinetics and Product Branching Fractions of Reactions between a Cation and a Radical: Ar<sup>+</sup> + CH<sub>3</sub> and O<sub>2</sub><sup>+</sup> + CH<sub>3</sub>","year":2015,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Atmospheric chemistry and aerosols","field":"Earth and Planetary Sciences","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Air Force Office of Scientific Research; National Research Council Canada","keywords":"Chemistry; Reaction rate constant; Branching (polymer chemistry); Kinetics; Branching fraction; Radical; Analytical Chemistry (journal); Ion; Electron transfer; Mass spectrometry; Chemical kinetics; Photochemistry; Physical chemistry; Atomic physics; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000380654,0.0006030122,0.0002404403,0.0002485188,0.0001632463,0.0002966393,0.0005373437,0.0004396733,0.001970711],"category_scores_gemma":[0.0007705179,0.0002102121,0.0002721938,0.0002105903,0.0002482639,0.0005661829,0.0002128323,0.0006164811,0.0006209074],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002881564,"about_ca_system_score_gemma":0.0001395311,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004992597,"about_ca_topic_score_gemma":0.0004755446,"domain_scores_codex":[0.9997357,0.00002269817,0.000007554683,0.00009920652,0.00009987577,0.00003503099],"domain_scores_gemma":[0.9994955,0.0002039793,0.000148382,0.00002450845,0.00009610329,0.00003150876],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003771683,0.00003501611,0.002779191,0.0001355037,0.00002223804,0.00004080515,0.00009414278,0.0007006777,0.9872085,0.0004553335,0.0001260611,0.008025311],"study_design_scores_gemma":[0.00001130717,0.0002674749,0.006742342,0.000006610817,0.00003035453,0.0002124615,0.00003971343,0.005359455,0.985564,0.0002580115,0.001495346,0.0000129981],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9599938,0.003574162,0.03230276,0.00006915886,0.00003655559,0.00007255594,0.0006877516,0.0003657119,0.0028976],"genre_scores_gemma":[0.9891644,0.001179364,0.007204477,0.00002357272,0.00001064279,0.00006057699,0.0004175541,0.0000534114,0.001885953],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001970711,"threshold_uncertainty_score":0.006592691,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01539059092788208,"score_gpt":0.2252387851897812,"score_spread":0.2098481942618991,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}