{"id":"W2320007961","doi":"10.1021/ic301385u","title":"Construction of (CuX)<sub>2<i>n</i></sub> Cluster-Containing (X = Br, I; <i>n</i> = 1, 2) Coordination Polymers Assembled by Dithioethers ArS(CH<sub>2</sub>)<sub><i>m</i></sub>SAr (Ar = Ph, <i>p</i>-Tol; <i>m</i> = 3, 5): Effect of the Spacer Length, Aryl Group, and Metal-to-Ligand Ratio on the Dimensionality, Cluster Nuclearity, and the Luminescence Properties of the Metal–Organic Frameworks","year":2012,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":89,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Chemistry; Ligand (biochemistry); Propane; Crystallography; Ribbon; Metal; Cubane; Coordination polymer; Copper; Stereochemistry; Bridging ligand; Cluster (spacecraft); Polymer; Crystal structure; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007653587,0.0004975382,0.0002331699,0.0001655636,0.0001610076,0.00036611,0.0004312151,0.0002489544,0.001054822],"category_scores_gemma":[0.000173009,0.0002274004,0.000220052,0.0002202489,0.000153725,0.0002335673,0.0003436599,0.0003198842,0.0003438829],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005149377,"about_ca_system_score_gemma":0.0003026434,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007446035,"about_ca_topic_score_gemma":0.00141033,"domain_scores_codex":[0.9998748,0.0000120103,0.00000784451,0.00005032578,0.00002140011,0.00003354057],"domain_scores_gemma":[0.9998785,0.000008154821,0.00004781564,0.00001298834,0.000009945323,0.00004258209],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001472353,0.000058217,0.0001993249,0.0001060367,0.00001898484,0.00008022669,0.00003837824,0.0007176781,0.9937921,0.00040347,0.0001547128,0.00428365],"study_design_scores_gemma":[0.00002485628,0.0003060965,0.00152427,0.000006141582,0.00001865505,0.0001187663,0.00001234303,0.002244374,0.9934006,0.0000433814,0.002287064,0.00001350298],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9898025,0.0004323001,0.006063445,0.00003693091,0.00002614275,0.00008902195,0.0002810669,0.0003364736,0.002932016],"genre_scores_gemma":[0.9861686,0.0002929646,0.01060421,0.0000216351,0.000007185603,0.00009526929,0.0003791477,0.00006068311,0.002370405],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001054822,"threshold_uncertainty_score":0.003736138,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007053258180790609,"score_gpt":0.1995230857032275,"score_spread":0.1924698275224369,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}