{"id":"W2320007961","doi":"10.1021/ic301385u","title":"Construction of (CuX)<sub>2<i>n</i></sub> Cluster-Containing (X = Br, I; <i>n</i> = 1, 2) Coordination Polymers Assembled by Dithioethers ArS(CH<sub>2</sub>)<sub><i>m</i></sub>SAr (Ar = Ph, <i>p</i>-Tol; <i>m</i> = 3, 5): Effect of the Spacer Length, Aryl Group, and Metal-to-Ligand Ratio on the Dimensionality, Cluster Nuclearity, and the Luminescence Properties of the Metal–Organic Frameworks","year":2012,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":89,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Chemistry; Ligand (biochemistry); Propane; Crystallography; Ribbon; Metal; Cubane; Coordination polymer; Copper; Stereochemistry; Bridging ligand; Cluster (spacecraft); Polymer; Crystal structure; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.002233205,0.0009117544,0.001252753,0.00005688403,0.0007581247,0.0001459735,0.00106588,0.0009411165,0.00004504732],"category_scores_gemma":[0.001430213,0.0005298462,0.0004957684,0.0009080119,0.001906677,0.0003583419,0.001006914,0.001843049,0.000007097156],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001519069,"about_ca_system_score_gemma":0.0001576873,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000056237,"about_ca_topic_score_gemma":0.00003037653,"domain_scores_codex":[0.9951261,0.000564322,0.001381316,0.0009442586,0.0012231,0.0007609231],"domain_scores_gemma":[0.993718,0.002271747,0.001606994,0.001875023,0.000277349,0.0002509128],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004586887,0.0002621833,0.001989978,0.000597503,0.0005189799,3.276235e-7,0.000819854,0.00001257371,0.9930642,0.0003676021,0.0004574313,0.00145072],"study_design_scores_gemma":[0.001956628,0.00005669916,0.000352937,0.0008404414,0.001044126,0.00009699498,0.0009750376,0.0002865267,0.9934899,0.0002312383,0.00009701703,0.0005724665],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9918036,0.002022502,0.000181248,0.003978245,0.0003106205,0.001298039,0.00009650986,0.00007357761,0.0002355937],"genre_scores_gemma":[0.9980279,0.0004307436,0.000038132,0.0009370065,0.0002214875,0.0001382157,0.00002136356,0.0001609044,0.00002424599],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006224237,"threshold_uncertainty_score":0.9997153,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007053258180790609,"score_gpt":0.1995230857032275,"score_spread":0.1924698275224369,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}