{"id":"W2320017342","doi":"10.1021/jp202478w","title":"Kinetics and Mechanism of OH Oxidation of Small Organic Dicarboxylic Acids in Ice: Comparison to Behavior in Aqueous Solution","year":2011,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Atmospheric chemistry and aerosols","field":"Earth and Planetary Sciences","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada; Canadian Foundation for Climate and Atmospheric Sciences","keywords":"Chemistry; Malonic acid; Succinic acid; Aqueous solution; Dicarboxylic acid; Kinetics; Malic acid; Inorganic chemistry; Organic acid; Organic chemistry; Citric acid","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001668592,0.0003738858,0.000262476,0.000128507,0.0001012785,0.0002325416,0.0002630268,0.0003273545,0.0007708784],"category_scores_gemma":[0.000215573,0.0001034601,0.0002344365,0.0001150848,0.0002108201,0.0003238444,0.0001909426,0.000379764,0.0002249403],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000309716,"about_ca_system_score_gemma":0.0001802374,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001150273,"about_ca_topic_score_gemma":0.0008011814,"domain_scores_codex":[0.9999032,0.000009123407,0.000005263099,0.00003405173,0.00002525507,0.00002309747],"domain_scores_gemma":[0.9998963,0.00002649883,0.00002766847,0.000007630199,0.00002526316,0.00001667031],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001266314,0.00001193715,0.001063899,0.0001129246,0.00001205178,0.00004725263,0.00003897935,0.000307922,0.9962768,0.00007353653,0.00002247156,0.001905691],"study_design_scores_gemma":[0.000007198578,0.000244402,0.00642785,0.00001036221,0.00001414904,0.00007910221,0.00006139465,0.002754183,0.9892429,0.00009095844,0.001059595,0.000007827445],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9876963,0.003314945,0.006801793,0.00006240512,0.00003067494,0.00006093649,0.0005883155,0.00003952987,0.001405036],"genre_scores_gemma":[0.9928707,0.002047692,0.003322287,0.00004809755,0.00001059454,0.00004196956,0.0004734918,0.00001368141,0.001171387],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001150273,"threshold_uncertainty_score":0.002578795,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0217817022230208,"score_gpt":0.2261114490516642,"score_spread":0.2043297468286434,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}