{"id":"W2320259907","doi":"10.1021/sc3001367","title":"Green Strategy Guided by Raman Spectroscopy for the Synthesis of Ammonium Carboxylated Nanocrystalline Cellulose and the Recovery of Byproducts","year":2012,"lang":"en","type":"article","venue":"ACS Sustainable Chemistry & Engineering","topic":"Advanced Cellulose Research Studies","field":"Materials Science","cited_by":72,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Research Council Canada","funders":"","keywords":"Microcrystalline cellulose; Cellulose; Nanocrystalline material; Nanomaterials; Raman spectroscopy; Chemistry; Cellulosic ethanol; Nanocellulose; Ammonium persulfate; Green chemistry; Persulfate; Chemical engineering; Sulfate; Ammonium; Microcrystalline; Materials science; Catalysis; Organic chemistry; Nanotechnology; Reaction mechanism","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002989247,0.0006020823,0.0003711304,0.0003384257,0.000162401,0.0002862309,0.0003818872,0.000439835,0.0005624311],"category_scores_gemma":[0.0001977378,0.0002351152,0.0004046606,0.0001842919,0.0002748854,0.0002974779,0.0003248875,0.0005800289,0.0003689349],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004475822,"about_ca_system_score_gemma":0.0004868906,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007609167,"about_ca_topic_score_gemma":0.002215936,"domain_scores_codex":[0.9997469,0.00003032265,0.00001636612,0.00004922153,0.0001166557,0.00004055917],"domain_scores_gemma":[0.9998813,0.00002359529,0.0000296352,0.00001982422,0.0000297367,0.00001597225],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000009012511,0.00001200494,0.00001671135,0.00002375524,0.000002005405,0.00002675453,0.000009717749,0.00009092423,0.9980277,0.0001537736,0.00002640024,0.001601086],"study_design_scores_gemma":[0.000002826659,0.00002784727,0.00009973795,0.000001337139,0.00000255121,0.00003782789,0.000005409102,0.0009115739,0.9982809,0.00003612148,0.0005896623,0.000004191962],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7909877,0.002562316,0.1967693,0.0004395823,0.0002165336,0.0004782573,0.000451715,0.0007574003,0.007337322],"genre_scores_gemma":[0.8054606,0.001938339,0.185847,0.0001915191,0.00002259998,0.0002525837,0.0002841547,0.0001000671,0.005903141],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007609167,"threshold_uncertainty_score":0.003247499,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00838871710642159,"score_gpt":0.2343086244975851,"score_spread":0.2259199073911635,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}