{"id":"W2320386283","doi":"10.1021/jp211528d","title":"Investigation of Aqueous-Phase Photooxidation of Glyoxal and Methylglyoxal by Aerosol Chemical Ionization Mass Spectrometry: Observation of Hydroxyhydroperoxide Formation","year":2012,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Atmospheric chemistry and aerosols","field":"Earth and Planetary Sciences","cited_by":89,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Glyoxal; Chemistry; Chemical ionization; Aerosol; Methylglyoxal; Aqueous solution; Mass spectrometry; Formic acid; Acetic acid; Aqueous two-phase system; Reagent; Atmospheric-pressure chemical ionization; Aldehyde; Iodide; Photochemistry; Inorganic chemistry; Chromatography; Organic chemistry; Ionization; Ion","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001607785,0.0004183871,0.0001673241,0.000261291,0.0001621299,0.0001655411,0.0002633114,0.0003811002,0.0006514169],"category_scores_gemma":[0.0001719974,0.00009550503,0.0002248958,0.0001591753,0.0001802769,0.0002649669,0.0001829328,0.0002757246,0.0001584631],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002648454,"about_ca_system_score_gemma":0.0001614319,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009043037,"about_ca_topic_score_gemma":0.0009438188,"domain_scores_codex":[0.999896,0.00001001464,0.000003546024,0.0000259072,0.00004894612,0.00001550362],"domain_scores_gemma":[0.9998816,0.00002741005,0.00003004262,0.000005329698,0.00004132184,0.00001422047],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005476735,0.00001234416,0.001089054,0.00004113551,0.00000960599,0.00005147758,0.00001755595,0.0001071122,0.9971563,0.0000369692,0.00002777836,0.001395889],"study_design_scores_gemma":[0.000005244935,0.0001174558,0.005841712,0.000002766123,0.00000980989,0.00009123584,0.00003255752,0.002571401,0.9906894,0.00005245878,0.0005814952,0.000004539702],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9902143,0.001073485,0.006773458,0.00004759725,0.00002777666,0.00004866868,0.0003059755,0.00006603506,0.001442677],"genre_scores_gemma":[0.9918134,0.0007194486,0.006419051,0.00005165223,0.00001683328,0.00002407887,0.0002205905,0.00001412219,0.0007209164],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009043037,"threshold_uncertainty_score":0.002179205,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01481147920359716,"score_gpt":0.2215550848505884,"score_spread":0.2067436056469913,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}