{"id":"W2320476341","doi":"10.1021/ef101050a","title":"Membrane Diffusion Measurements Do Not Detect Exchange between Asphaltene Aggregates and Solution Phase","year":2010,"lang":"en","type":"article","venue":"Energy & Fuels","topic":"Petroleum Processing and Analysis","field":"Chemistry","cited_by":59,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Asphaltene; Chemistry; Toluene; Diffusion; Phase (matter); Membrane; Permeation; Chemical engineering; Analytical Chemistry (journal); Chromatography; Organic chemistry; Thermodynamics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002353274,0.0002231507,0.0002883412,0.00009702958,0.000264686,0.00009417997,0.0001837153,0.0001897934,0.0005131793],"category_scores_gemma":[0.00008125055,0.0002002732,0.00009426729,0.0001416336,0.00007514642,0.000146041,0.00006371966,0.0002168798,0.000008247179],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002707096,"about_ca_system_score_gemma":0.00002535311,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000242747,"about_ca_topic_score_gemma":0.0001294348,"domain_scores_codex":[0.998623,0.00002495395,0.0002485267,0.0004012259,0.000370912,0.0003313638],"domain_scores_gemma":[0.9992256,0.00004898209,0.0001649788,0.0003011184,0.00007476441,0.0001845584],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002003993,0.00004766769,0.0008270966,0.00005312964,0.00005483443,0.000004659859,0.00003319724,3.898488e-7,0.7010097,0.000004200192,0.00001305135,0.2979321],"study_design_scores_gemma":[0.001380815,0.00002739466,0.0001799611,0.00007564631,0.000160497,0.000006855768,0.000009965993,0.00009769374,0.9816738,0.0000778984,0.01607361,0.0002358948],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9918256,0.001432875,0.0002767513,0.0001542258,0.00008183351,0.000005089483,0.00002147915,0.0001162606,0.006085865],"genre_scores_gemma":[0.9940614,0.0003023427,0.0002242486,0.00006395714,0.0005402461,0.00001729744,0.00006630374,0.00002840861,0.004695819],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2976962,"threshold_uncertainty_score":0.8166904,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02481454733955526,"score_gpt":0.2612706031313187,"score_spread":0.2364560557917634,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}