{"id":"W2320476341","doi":"10.1021/ef101050a","title":"Membrane Diffusion Measurements Do Not Detect Exchange between Asphaltene Aggregates and Solution Phase","year":2010,"lang":"en","type":"article","venue":"Energy & Fuels","topic":"Petroleum Processing and Analysis","field":"Chemistry","cited_by":59,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Asphaltene; Chemistry; Toluene; Diffusion; Phase (matter); Membrane; Permeation; Chemical engineering; Analytical Chemistry (journal); Chromatography; Organic chemistry; Thermodynamics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004139369,0.0005593126,0.0006612401,0.0003143561,0.0003421864,0.0007210664,0.0004607587,0.0007031541,0.0008616733],"category_scores_gemma":[0.0008902879,0.0003313443,0.0002938151,0.0003810999,0.0004562259,0.001169531,0.0005028544,0.001097555,0.0004915939],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005625193,"about_ca_system_score_gemma":0.0002921021,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001481899,"about_ca_topic_score_gemma":0.002310587,"domain_scores_codex":[0.9992377,0.00008746979,0.00005557331,0.0001855494,0.0003233441,0.00011042],"domain_scores_gemma":[0.9989729,0.0003920375,0.0002907438,0.00009001225,0.0002114605,0.00004286435],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003035069,0.000009603989,0.0004334222,0.00009743029,0.0000106276,0.00002447738,0.00004857372,0.00003032384,0.9975393,0.00006257019,0.00002741807,0.001685937],"study_design_scores_gemma":[0.0000059945,0.00006922243,0.003188695,0.000008501024,0.00001800642,0.0001153919,0.00007673721,0.001117552,0.9938484,0.00006335244,0.001479203,0.000008899012],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9550735,0.003964574,0.03675845,0.0002841517,0.0001171344,0.0000732505,0.0005668044,0.0003276954,0.002834509],"genre_scores_gemma":[0.9801879,0.002393787,0.01416668,0.0001031524,0.00002153774,0.0000866241,0.00046862,0.00007049571,0.002501248],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001481899,"threshold_uncertainty_score":0.004081368,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02481454733955526,"score_gpt":0.2612706031313187,"score_spread":0.2364560557917634,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}