{"id":"W2320493809","doi":"10.1021/ol4034463","title":"Autotandem Catalysis with Ruthenium: Remote Hydroesterification of Allylic Amides","year":2013,"lang":"en","type":"article","venue":"Organic Letters","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":41,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada; Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung","keywords":"Chemistry; Allylic rearrangement; Isomerization; Catalysis; Ruthenium; Tandem; Olefin fiber; Combinatorial chemistry; Hydride; Acetic acid; Organic chemistry; Hydrogen","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00008286875,0.0001564901,0.0002228112,0.0001279009,0.00005858048,0.00003818615,0.0002626429,0.00007321715,0.002512795],"category_scores_gemma":[0.0000422081,0.0001296866,0.00008028436,0.0006296876,0.00008041954,0.0001717783,0.00003264317,0.0001050056,0.0002931641],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000967282,"about_ca_system_score_gemma":0.00003164539,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002255953,"about_ca_topic_score_gemma":0.00001651513,"domain_scores_codex":[0.9989343,0.00001605631,0.0003002058,0.000277705,0.0002747056,0.0001970876],"domain_scores_gemma":[0.9990241,0.000042979,0.0002369971,0.0005348651,0.00007766121,0.00008342072],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000004549343,0.00003124315,0.001272465,0.00003124778,0.0001509809,0.000002166588,0.0003300814,0.00001452521,0.9909112,0.0000152085,0.0005409647,0.006695353],"study_design_scores_gemma":[0.0004211488,0.000011504,0.001546473,0.000021257,0.0001541345,0.00001735511,0.0002436189,0.001232751,0.9954728,0.00002746223,0.0006174809,0.0002339891],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9924783,0.00003963499,0.003136271,0.002284912,0.00001573523,0.0000647065,0.000003859075,0.00009832372,0.00187832],"genre_scores_gemma":[0.9981797,0.00001320479,0.000545531,0.0005655189,0.00004503865,0.000007956422,0.00008676101,0.00003384359,0.00052246],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006461364,"threshold_uncertainty_score":0.998399,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005784218231073379,"score_gpt":0.1867246849781979,"score_spread":0.1809404667471245,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}