{"id":"W2320507318","doi":"10.1021/cs200149v","title":"Comparison of Copper and Vanadium Homogeneous Catalysts for Aerobic Oxidation of Lignin Models","year":2011,"lang":"en","type":"article","venue":"ACS Catalysis","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":183,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Ketone; Chemistry; Catalysis; Vanadium; Formic acid; Benzoic acid; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003741029,0.000414292,0.0003465592,0.0005638572,0.0001962695,0.0006104934,0.0007145015,0.000274,0.0005943768],"category_scores_gemma":[0.0005224307,0.0002765218,0.000261208,0.0005031904,0.0001622589,0.0002872641,0.0004091154,0.000299354,0.0002423625],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003927632,"about_ca_system_score_gemma":0.000236442,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00234343,"about_ca_topic_score_gemma":0.004699037,"domain_scores_codex":[0.99958,0.00006449255,0.00004180301,0.00006579667,0.000134249,0.0001136487],"domain_scores_gemma":[0.9997999,0.00004363871,0.00003409266,0.00002582206,0.00005561445,0.00004095183],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000491707,0.0001356599,0.0008532405,0.0002484889,0.00007169372,0.0001351795,0.000059627,0.001185213,0.9803475,0.0003890275,0.000201042,0.01588179],"study_design_scores_gemma":[0.00002056386,0.0005085359,0.001427733,0.00001118767,0.00004750053,0.00007951928,0.0000467665,0.00258571,0.992755,0.00005092409,0.002458954,0.000007566231],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9903103,0.003599786,0.003025298,0.00004705608,0.00003795955,0.00002635419,0.0001240217,0.00006300836,0.002766235],"genre_scores_gemma":[0.9941037,0.001775198,0.002336352,0.00001014532,0.00001224712,0.00001384016,0.0002778702,0.00002512629,0.001445518],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00234343,"threshold_uncertainty_score":0.004659534,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.06042264250490881,"score_gpt":0.2850312957456775,"score_spread":0.2246086532407687,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}