{"id":"W2320676121","doi":"10.1021/om400544z","title":"Selective and Nonselective Aza-Michael Additions Catalyzed by a Chiral Zirconium Bis-Diketiminate Complex","year":2013,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal; Centre in Green Chemistry and Catalysis","funders":"","keywords":"Chemistry; Methacrylonitrile; Morpholine; Nucleophile; Medicinal chemistry; Deprotonation; Benzylamine; Michael reaction; Catalysis; Aniline; Amine gas treating; Polymer chemistry; Acrylonitrile; Reactivity (psychology); Methyl acrylate; Reaction rate constant; Trifluoromethanesulfonate; Organic chemistry; Kinetics; Copolymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002417031,0.0005450298,0.0002496906,0.0001925359,0.0001222987,0.0002406238,0.0004808955,0.0002387042,0.001105364],"category_scores_gemma":[0.000190879,0.0002014683,0.0001710257,0.0001525506,0.0001785767,0.0002365692,0.0002553538,0.0003658647,0.0005218703],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000400589,"about_ca_system_score_gemma":0.0002179239,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005471342,"about_ca_topic_score_gemma":0.0009132156,"domain_scores_codex":[0.9998038,0.00002531219,0.00001640956,0.00005657921,0.0000442003,0.00005356684],"domain_scores_gemma":[0.9999274,0.00001170427,0.00002452489,0.000009469048,0.00001107555,0.00001579988],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008725156,0.0000145743,0.00006733039,0.0000438296,0.000007850297,0.00006244204,0.00001901979,0.00008550295,0.9975682,0.0003404158,0.00005647553,0.001647103],"study_design_scores_gemma":[0.00001406423,0.00009116847,0.0002551748,0.0000020263,0.000008568893,0.0001066805,0.000004858427,0.0004801202,0.997668,0.00002419397,0.001339879,0.000005307897],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.978621,0.0009019549,0.01318789,0.0001178442,0.00005152147,0.00008314734,0.0002229578,0.0002227179,0.006590944],"genre_scores_gemma":[0.9911243,0.0003587678,0.005503442,0.00001500677,0.000007002915,0.00001731928,0.0001905874,0.00002444405,0.002759219],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001105364,"threshold_uncertainty_score":0.003697813,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00884573687751676,"score_gpt":0.2003871606878837,"score_spread":0.1915414238103669,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}