{"id":"W2320977696","doi":"10.1021/jp308395x","title":"Nucleation of Gas Hydrates within Constant Energy Systems","year":2013,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry B","topic":"Methane Hydrates and Related Phenomena","field":"Environmental Science","cited_by":84,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada; Western Canada Research Grid","keywords":"Nucleation; Clathrate hydrate; Isothermal process; Hydrate; Amorphous solid; Thermodynamics; Molecular dynamics; Work (physics); Chemical physics; Constant (computer programming); Materials science; Chemistry; Physical chemistry; Crystallography; Computational chemistry; Physics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001931838,0.0000804153,0.000166368,0.000004851838,0.00003804492,0.00001298585,0.0002103611,0.00003370298,0.0005437353],"category_scores_gemma":[0.00001729933,0.00004277709,0.00006038999,0.00009509161,0.0001875351,0.0001024535,0.00004508982,0.000148054,0.00003590304],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003707226,"about_ca_system_score_gemma":0.000009154035,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001816574,"about_ca_topic_score_gemma":2.852813e-7,"domain_scores_codex":[0.9992502,0.00005038383,0.0002815061,0.00005485141,0.0002608831,0.0001021944],"domain_scores_gemma":[0.9992738,0.00009108583,0.0004115187,0.0001228829,0.00002773523,0.00007295339],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000016809,0.00007146185,0.00005481959,0.00001243258,0.00003257982,0.000001024063,0.0004108834,0.024751,0.9738376,0.0001221606,0.0004761673,0.0002130644],"study_design_scores_gemma":[0.0003793722,0.0001555347,0.0001368702,0.00008009802,0.00008934729,0.00007473842,0.0007821553,0.06395431,0.9278225,0.005955684,0.000429365,0.0001399733],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9868238,0.00009698391,0.00007276732,0.0001298848,0.00003789245,0.00003362425,9.958623e-7,0.000003321542,0.01280075],"genre_scores_gemma":[0.9993602,0.00002410898,0.00002414458,0.00001639347,0.0001066489,8.742498e-7,5.74261e-7,0.000006600102,0.0004604401],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04601505,"threshold_uncertainty_score":0.5953521,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005058290619613956,"score_gpt":0.1861863325974176,"score_spread":0.1811280419778037,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}