{"id":"W2320999309","doi":"10.1021/ja208902t","title":"Phase Separation As a Strategy Toward Controlling Dilution Effects in Macrocyclic Glaser-Hay Couplings","year":2011,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":88,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal; Centre in Green Chemistry and Catalysis","funders":"Natural Sciences and Engineering Research Council of Canada; Fonds Québécois de la Recherche sur la Nature et les Technologies","keywords":"Chemistry; Dilution; Catalysis; Combinatorial chemistry; Phase (matter); Derivative (finance); Ligand (biochemistry); Solvent; Substrate (aquarium); PEG ratio; Chemical engineering; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002835685,0.0001921905,0.0004396667,0.00002306443,0.00009186929,0.00005055436,0.0003591792,0.000106145,0.00005752457],"category_scores_gemma":[0.0002665383,0.0001471675,0.0005817431,0.0003119872,0.0003552831,0.0001634908,0.00006422496,0.000764421,0.000008663495],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000526018,"about_ca_system_score_gemma":0.0001509526,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003317195,"about_ca_topic_score_gemma":0.000003053564,"domain_scores_codex":[0.9985573,0.000003807038,0.0005740859,0.0001984412,0.0003619755,0.0003043317],"domain_scores_gemma":[0.998288,0.000245166,0.0009675532,0.0002403164,0.0001275944,0.0001314152],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003399184,0.0005197501,0.0009460053,0.00004093553,0.0001076217,0.000009375198,0.001004784,0.0001705699,0.9954575,0.00001496844,0.0002640364,0.001124533],"study_design_scores_gemma":[0.003264338,0.0001162915,0.0004237688,0.0001188653,0.000143244,0.0001378419,0.0008791575,0.007878912,0.9860995,0.0006229897,0.000131532,0.0001835493],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9988821,0.0000927477,0.0004109729,0.0002150503,0.0001026373,0.00008292434,0.000007004463,0.00002670729,0.0001798486],"genre_scores_gemma":[0.9991586,0.00004873624,0.0002435799,0.0001934878,0.0002666555,0.000008327313,0.000004081246,0.00002359584,0.00005288981],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009357992,"threshold_uncertainty_score":0.6001316,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01871514658360795,"score_gpt":0.3154648307866098,"score_spread":0.2967496842030019,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}