{"id":"W2321114398","doi":"10.1021/ja402964h","title":"C–H Bond Activation by Radical Ion Pairs Derived from R<sub>3</sub>P/Al(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub> Frustrated Lewis Pairs and N<sub>2</sub>O","year":2013,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":187,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor; University of Toronto","funders":"","keywords":"Chemistry; Bromobenzene; Toluene; Lewis acids and bases; Frustrated Lewis pair; Medicinal chemistry; Nap; Ion; Salt (chemistry); Stereochemistry; Crystallography; Catalysis; Physical chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008400885,0.0003110874,0.0001678077,0.00009784156,0.0001615463,0.0001977557,0.0004301028,0.0002954347,0.002391307],"category_scores_gemma":[0.0001327762,0.0001300099,0.0001943916,0.00008504104,0.0001756012,0.0002891738,0.0003667554,0.0002954299,0.0003398109],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001662886,"about_ca_system_score_gemma":0.0001074169,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002349986,"about_ca_topic_score_gemma":0.000418989,"domain_scores_codex":[0.9999238,0.000006088914,0.000002960241,0.00001796804,0.00001834066,0.00003075501],"domain_scores_gemma":[0.9999489,0.000007609671,0.00001754544,0.00000777527,0.000006196657,0.00001209132],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001759675,0.00002096283,0.0002408133,0.0001071093,0.00001705003,0.0001224937,0.00006224448,0.0002860369,0.9937767,0.0006809882,0.00021841,0.004291256],"study_design_scores_gemma":[0.00001816614,0.0002591316,0.0005416653,0.000002025879,0.000008010786,0.000136814,0.00002295208,0.001172196,0.9960601,0.0001127042,0.001657066,0.000009167994],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9940342,0.0002483265,0.002553374,0.00002908184,0.00002728241,0.00002420726,0.00007166118,0.0001042767,0.002907599],"genre_scores_gemma":[0.9974418,0.00008048883,0.001271844,0.00001914943,0.000005851185,0.00001140398,0.00007840814,0.00001262816,0.001078491],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002391307,"threshold_uncertainty_score":0.007999718,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006493648370686039,"score_gpt":0.2037292358239511,"score_spread":0.1972355874532651,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}