{"id":"W2321194256","doi":"10.1021/jp4089904","title":"Hydrated Electrons React with High Specificity with Cisplatin Bound to Single-Stranded DNA","year":2013,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry B","topic":"DNA and Nucleic Acid Chemistry","field":"Biochemistry, Genetics and Molecular Biology","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"Canadian Institutes of Health Research","keywords":"Chemistry; Oligonucleotide; Solvated electron; Radical; Radiolysis; Guanine; Ethylenediaminetetraacetic acid; DNA; DNA damage; Adduct; Cisplatin; Photochemistry; Electron; Irradiation; Yield (engineering); Inorganic chemistry; Oxygen; Radiochemistry; Chelation; Materials science; Biochemistry; Organic chemistry; Nucleotide","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002967134,0.0003283215,0.0003189201,0.0001891881,0.0001264353,0.0002431869,0.0002543406,0.0003237021,0.001002208],"category_scores_gemma":[0.0003891191,0.0003173254,0.0001773923,0.0001360605,0.0003036159,0.0001682965,0.000331723,0.0003524394,0.0002330234],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002505816,"about_ca_system_score_gemma":0.0001472588,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003484119,"about_ca_topic_score_gemma":0.0005540667,"domain_scores_codex":[0.9997264,0.00008349337,0.00001819484,0.00007017958,0.00006204256,0.00003959206],"domain_scores_gemma":[0.9997426,0.0001064888,0.00004395405,0.00003025597,0.00003604111,0.00004070866],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006947014,0.000005921868,0.0001504543,0.00002305167,0.000007505609,0.00002576438,0.00002065912,0.00008269279,0.9991888,0.00003002198,0.000005411549,0.0003902556],"study_design_scores_gemma":[0.000007037541,0.0001886856,0.0009727199,0.000002839711,0.000008386213,0.00006745678,0.000009376765,0.0002198863,0.9982292,0.00001523286,0.0002765021,0.000002748694],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9955617,0.0004866944,0.003385715,0.00002459853,0.000007191075,0.00002010805,0.00003521908,0.00002759412,0.0004510792],"genre_scores_gemma":[0.9932033,0.0004635554,0.004412144,0.00003669322,0.000006481613,0.00002442322,0.0001820906,0.00001774358,0.001653549],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001002208,"threshold_uncertainty_score":0.003352761,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004791871129347858,"score_gpt":0.1952582700551556,"score_spread":0.1904663989258077,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}