{"id":"W2321242693","doi":"10.1021/ic301559s","title":"Diimine Triscarbonyl Re(I) of Isomeric Pyridyl-fulvene Ligands: an Electrochemical, Spectroscopic, and Computational Investigation","year":2012,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Molecular Junctions and Nanostructures","field":"Engineering","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Fulvene; Diimine; Electrochemistry; Photochemistry; Computational chemistry; Stereochemistry; Organic chemistry; Physical chemistry; Electrode","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001207624,0.0001820612,0.0003342862,0.00006918824,0.00008768877,0.0003630655,0.0004880597,0.0002969837,0.0009696767],"category_scores_gemma":[0.000217375,0.0001032238,0.0001325955,0.0001755948,0.00009500717,0.0003066416,0.0001505846,0.000265042,0.0001635261],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003073097,"about_ca_system_score_gemma":0.0001665958,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001263575,"about_ca_topic_score_gemma":0.001862904,"domain_scores_codex":[0.9999595,0.000006321553,0.000001327602,0.000007584438,0.00001414599,0.00001108143],"domain_scores_gemma":[0.9999564,0.00001648079,0.000008407311,0.000004009609,0.000009443016,0.000005199599],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00108636,0.0005555336,0.004302452,0.002489674,0.0001931506,0.001324319,0.000223553,0.2807147,0.5732281,0.02072173,0.003466593,0.1116938],"study_design_scores_gemma":[0.000148768,0.0007781944,0.001790666,0.00003358075,0.00007712792,0.0005032999,0.0002636275,0.7569215,0.2232613,0.001273783,0.01491644,0.00003175755],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9777637,0.001610138,0.01187912,0.000181863,0.00002055466,0.00003054945,0.0002042609,0.0001598948,0.008149949],"genre_scores_gemma":[0.9830405,0.001147574,0.01333441,0.00005612681,0.000005457771,0.00003888754,0.0002303515,0.00002579808,0.002120692],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001263575,"threshold_uncertainty_score":0.003243923,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005248736861471097,"score_gpt":0.1967552130462369,"score_spread":0.1915064761847658,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}