{"id":"W2321369658","doi":"10.1021/ic301684h","title":"Reversible Double Oxidation and Protonation of the Non-Innocent Bridge in a Nickel(II) Salophen Complex","year":2012,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Metal-Catalyzed Oxygenation Mechanisms","field":"Chemistry","cited_by":41,"is_retracted":false,"has_abstract":true,"ca_institutions":"Concordia University","funders":"Centre National de la Recherche Scientifique","keywords":"Chemistry; Protonation; Nickel; Deprotonation; Ligand (biochemistry); Electron transfer; Photochemistry; Yield (engineering); Redox; Singlet state; Medicinal chemistry; Inorganic chemistry; Organic chemistry; Excited state","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009435359,0.0001614648,0.0001468728,0.00008744712,0.0001270398,0.0002130963,0.0003073557,0.0001871436,0.001134782],"category_scores_gemma":[0.0001495762,0.00008193675,0.00006905345,0.0001220215,0.0001921544,0.0001637255,0.0002412245,0.0002979883,0.000166811],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002433319,"about_ca_system_score_gemma":0.0001408197,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000550646,"about_ca_topic_score_gemma":0.001116235,"domain_scores_codex":[0.9999024,0.0000092348,0.000003827563,0.0000174938,0.000034608,0.00003248275],"domain_scores_gemma":[0.9999481,0.00001094671,0.00001110575,0.000008523917,0.000006809106,0.00001453448],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000129531,0.00001723425,0.0001467463,0.00003362375,0.000004819565,0.00009908558,0.00006893849,0.00008617165,0.9973378,0.0002710003,0.0000665759,0.001738552],"study_design_scores_gemma":[0.00001322382,0.0000991151,0.0005801655,0.000001579242,0.000003263839,0.00005762007,0.00002486202,0.0006018386,0.9978975,0.00004222447,0.0006760284,0.000002663235],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9974996,0.000103539,0.001021419,0.00003644672,0.00000709017,0.000006546027,0.00002966604,0.00002659911,0.001269077],"genre_scores_gemma":[0.9985976,0.00004998759,0.0004120696,0.000009441729,0.00000158616,0.000003975016,0.00004315224,0.000006256799,0.0008760162],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001134782,"threshold_uncertainty_score":0.00379622,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02642616607455076,"score_gpt":0.2491159531707332,"score_spread":0.2226897870961825,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}