{"id":"W2321449444","doi":"10.1021/jo301393s","title":"The Galactosamine Residue in Mycobacterial Arabinogalactan Is α-Linked","year":2012,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":22,"is_retracted":false,"has_abstract":true,"ca_institutions":"Alberta Glycomics Centre; University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada; Alberta Glycomics Centre; Colorado State University","keywords":"Chemistry; Arabinogalactan; Residue (chemistry); Moiety; Trisaccharide; Stereochemistry; Galactosamine; Polysaccharide; Tetrasaccharide; Substituent; Carbohydrate conformation; Nuclear magnetic resonance spectroscopy; Biochemistry; Galactose","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001031606,0.0003611227,0.0001185068,0.0002196041,0.0002218401,0.0002289252,0.0001782538,0.000210802,0.0005040716],"category_scores_gemma":[0.0001086555,0.0001073653,0.0001337632,0.0003411617,0.0002034012,0.0002048756,0.0002386586,0.0002987561,0.000359196],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002636316,"about_ca_system_score_gemma":0.0002831139,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006119002,"about_ca_topic_score_gemma":0.0009052275,"domain_scores_codex":[0.9999278,0.00001316811,0.000006491892,0.00001758623,0.00001912998,0.00001596006],"domain_scores_gemma":[0.9999453,0.000004702145,0.00001698749,0.000008022553,0.000006281505,0.00001864152],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009731286,0.00001104292,0.0003619869,0.00007682239,0.000005216121,0.0001110533,0.00003180399,0.0001135457,0.9909866,0.0005132827,0.00003779465,0.007653512],"study_design_scores_gemma":[0.000007539807,0.0002774923,0.002746847,0.00001751089,0.00001785916,0.0004251789,0.00002618763,0.0002441702,0.9871712,0.000222803,0.008833569,0.000009543252],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9772882,0.006649298,0.009455981,0.0001457494,0.00007630138,0.00005052138,0.0003287613,0.00006903835,0.005936144],"genre_scores_gemma":[0.9826835,0.003755745,0.009498768,0.00009178581,0.00002125623,0.00002885215,0.0004862416,0.00001267891,0.003421186],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0006119002,"threshold_uncertainty_score":0.001912773,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01061184830087731,"score_gpt":0.2165412723365644,"score_spread":0.2059294240356871,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}