{"id":"W2321658252","doi":"10.1021/om500757r","title":"Benzothiaoline Three-Coordinated Organoboron Compounds with a B═N Bond: Dual Emission and Temperature-Dependent Excimer Fluorescence","year":2014,"lang":"en","type":"article","venue":"Organometallics","topic":"Luminescence and Fluorescent Materials","field":"Materials Science","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Excimer; Intramolecular force; Fluorescence; Photochemistry; Intermolecular force; Monomer; Molecule; Moiety; Emission spectrum; Stereochemistry; Organic chemistry; Spectral line; Polymer","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001254146,0.0002682004,0.0002669547,0.0001355106,0.0001064222,0.0001958065,0.0002457026,0.0002092369,0.0006819103],"category_scores_gemma":[0.000129109,0.0001452123,0.00009234766,0.0001823701,0.0001395229,0.0001635902,0.0001480697,0.0002180981,0.0001967816],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003482004,"about_ca_system_score_gemma":0.0001342843,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006086143,"about_ca_topic_score_gemma":0.001932915,"domain_scores_codex":[0.9999052,0.00002243542,0.000006592925,0.00001783203,0.00002227323,0.00002569218],"domain_scores_gemma":[0.9999218,0.00001110472,0.00003226781,0.000005659752,0.00001382574,0.00001529133],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009228162,0.00001322227,0.00007375984,0.00007625271,0.000005989994,0.00002580589,0.00001627516,0.0001661465,0.9983869,0.0001273309,0.00004004215,0.0009760942],"study_design_scores_gemma":[0.00002234999,0.0003441726,0.0008657229,0.000005654244,0.00001193263,0.00005328406,0.000010247,0.0006175577,0.9962677,0.00001535701,0.001777968,0.000008093956],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9954157,0.001028477,0.001730949,0.00003651551,0.00001114057,0.00002312666,0.000167914,0.00005338135,0.001532802],"genre_scores_gemma":[0.9952421,0.0007215734,0.0023205,0.00002031164,0.000004687274,0.00003036807,0.0001814952,0.00001614324,0.001462732],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0006819103,"threshold_uncertainty_score":0.002526343,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007180427180331225,"score_gpt":0.2060413471835656,"score_spread":0.1988609200032344,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}