{"id":"W2321818205","doi":"10.1021/om4002846","title":"Highly Congested Donor–Acceptor P–B Compound: Synthesis and Properties of a BMes<sub>2</sub>- and a PPh<sub>2</sub>-Functionalized 1,8-Naphthalene","year":2013,"lang":"en","type":"article","venue":"Organometallics","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":43,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Killam Trusts","keywords":"Chemistry; Molecule; Naphthalene; Reactivity (psychology); Crystallography; Crystal structure; Halogen; Acceptor; Halogen bond; Crystal (programming language); Stereochemistry; Single crystal; Hydrogen bond; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001820126,0.0006974602,0.0009918105,0.0001665244,0.0002360247,0.0002353305,0.0003838539,0.0004963432,0.002307149],"category_scores_gemma":[0.000342457,0.0006446577,0.000178831,0.0003875575,0.0007123247,0.0004491605,0.0003351583,0.0004006317,0.0001368784],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001418197,"about_ca_system_score_gemma":0.0001834977,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006337469,"about_ca_topic_score_gemma":0.0000250306,"domain_scores_codex":[0.9970112,0.00006493714,0.0008607249,0.000899703,0.000529538,0.0006339226],"domain_scores_gemma":[0.9977558,0.0002808017,0.0004284872,0.0007345875,0.0003339877,0.0004662985],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009444164,0.0002863705,0.004621804,0.001035908,0.0003670778,0.00001002472,0.0002224205,6.862658e-7,0.9869207,0.00006193964,0.000347839,0.006030782],"study_design_scores_gemma":[0.001401759,0.00004300653,0.004321577,0.000170667,0.00026003,0.0001588097,0.0004428179,0.00004622024,0.9912059,0.00006768908,0.001142407,0.0007391582],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9949846,0.002702697,0.000007485458,0.000585194,0.0001287894,0.0003340959,0.0001109829,0.0002427573,0.0009034247],"genre_scores_gemma":[0.99713,0.001699366,0.0001330257,0.0001680983,0.0002083325,0.0001535241,0.00005409509,0.0001563477,0.0002972281],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005291624,"threshold_uncertainty_score":0.9996005,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01323056742981513,"score_gpt":0.1929648847881182,"score_spread":0.1797343173583031,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}