{"id":"W2321818205","doi":"10.1021/om4002846","title":"Highly Congested Donor–Acceptor P–B Compound: Synthesis and Properties of a BMes<sub>2</sub>- and a PPh<sub>2</sub>-Functionalized 1,8-Naphthalene","year":2013,"lang":"en","type":"article","venue":"Organometallics","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":43,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Killam Trusts","keywords":"Chemistry; Molecule; Naphthalene; Reactivity (psychology); Crystallography; Crystal structure; Halogen; Acceptor; Halogen bond; Crystal (programming language); Stereochemistry; Single crystal; Hydrogen bond; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007748592,0.0001912755,0.0001681699,0.00008487901,0.0001046758,0.0002259134,0.0001926835,0.000238696,0.001885495],"category_scores_gemma":[0.00008312107,0.0001000959,0.0000697127,0.0001334345,0.0001378751,0.0002544597,0.0001164155,0.0002408536,0.0003724851],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001918047,"about_ca_system_score_gemma":0.00009752094,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000353461,"about_ca_topic_score_gemma":0.0005694838,"domain_scores_codex":[0.9999629,0.000003984834,0.000001943316,0.000010928,0.00001139182,0.000008797377],"domain_scores_gemma":[0.9999614,0.00000665098,0.00001316481,0.00000331061,0.000005090795,0.00001044183],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001475791,0.00003393416,0.0001252849,0.00009141353,0.000009525163,0.00006635266,0.00001285887,0.0005452137,0.9964611,0.0003026625,0.00008289077,0.002121225],"study_design_scores_gemma":[0.00003750122,0.001009099,0.001748316,0.000008455219,0.00002088117,0.0001798703,0.00001886378,0.002554099,0.9905033,0.00005616355,0.003849205,0.00001423788],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9967113,0.0005856527,0.0006565076,0.00002968392,0.000006959614,0.00001681612,0.0002177191,0.00002213018,0.001753123],"genre_scores_gemma":[0.9969317,0.0004800886,0.001183431,0.00001563142,0.000004526953,0.00001667836,0.0001953553,0.000009200078,0.001163339],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001885495,"threshold_uncertainty_score":0.006307662,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01323056742981513,"score_gpt":0.1929648847881182,"score_spread":0.1797343173583031,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}