{"id":"W2321897794","doi":"10.1016/j.molcata.2016.03.045","title":"Synthesis of polystyrene-supported Pd(II)-NHC complex derived from theophylline as an efficient and reusable heterogeneous catalyst for the Heck-Matsuda cross-coupling reaction","year":2016,"lang":"en","type":"article","venue":"Journal of Molecular Catalysis A Chemical","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":44,"is_retracted":false,"has_abstract":false,"ca_institutions":"","funders":"University of British Columbia","keywords":"Polystyrene; Catalysis; Palladium; Fourier transform infrared spectroscopy; Chemistry; Heck reaction; Coupling reaction; Polymer; Polymer chemistry; Carbene; Heterogeneous catalysis; Thermal stability; Nuclear chemistry; Materials science; Organic chemistry; Chemical engineering","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0005717935,0.0003701983,0.0008119258,0.0001448976,0.0002705783,0.0001143417,0.0006230443,0.0002602859,0.0001389468],"category_scores_gemma":[0.001446948,0.0002488601,0.0006994427,0.0002286526,0.0004642365,0.0001614602,0.0001987196,0.0002794183,0.000004784765],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002442393,"about_ca_system_score_gemma":0.0001623364,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003421615,"about_ca_topic_score_gemma":0.00001536299,"domain_scores_codex":[0.9970982,0.00000528798,0.001283164,0.0005296516,0.0006797726,0.0004039161],"domain_scores_gemma":[0.9957483,0.001054466,0.001267946,0.001025841,0.0006282892,0.0002751648],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005993127,0.0003940959,0.000245931,0.00005231527,0.0009119003,0.00003868496,0.0001517483,0.001054178,0.9954539,0.000008929738,0.00001493657,0.001074083],"study_design_scores_gemma":[0.001277089,0.0000575869,0.0001763517,0.0001606281,0.001296262,0.0004767785,0.0001873168,0.006796281,0.9890327,0.0001357683,0.0001187992,0.0002844084],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9967813,0.0004803727,0.001858378,0.0003471391,0.00008375249,0.0001397899,0.000261618,0.00003231184,0.00001533133],"genre_scores_gemma":[0.9989295,0.00006288018,0.0004564177,0.00002916192,0.0002310927,0.00002854868,0.000151415,0.00007485801,0.00003609891],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006421154,"threshold_uncertainty_score":0.9999964,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01450259204861741,"score_gpt":0.2772765574744335,"score_spread":0.262773965425816,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}