{"id":"W2321942339","doi":"10.1021/jp205962g","title":"In Situ High-Pressure and Low-Temperature Study of Ammonia Borane by Raman Spectroscopy","year":2011,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry C","topic":"Hydrogen Storage and Materials","field":"Materials Science","cited_by":34,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Ammonia borane; Raman spectroscopy; Diamond anvil cell; Isothermal process; Phase diagram; Ambient pressure; Analytical Chemistry (journal); Phase (matter); Chemistry; Hydrogen storage; Cryostat; Phase transition; Borane; Materials science; Hydrogen; High pressure; Thermodynamics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003621831,0.0001217088,0.0003607781,0.00001090059,0.00003432603,0.00002109312,0.0003088383,0.00004862265,0.0001322354],"category_scores_gemma":[0.00002272915,0.00007487858,0.00003293164,0.00006935462,0.00008756161,0.0001385503,0.00006602595,0.0001824888,0.000003579655],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000009956367,"about_ca_system_score_gemma":0.00002283372,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00009231355,"about_ca_topic_score_gemma":0.000003818354,"domain_scores_codex":[0.9991261,0.00009656454,0.000292414,0.0001030038,0.0002329697,0.0001489699],"domain_scores_gemma":[0.999375,0.00004089778,0.0002614915,0.0001956863,0.00005747546,0.00006942354],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002747345,0.0006437543,0.00001470986,0.00005827138,0.00002286974,0.00002838694,0.00266713,0.000007376948,0.995888,0.000003659454,0.0003874058,0.000003696229],"study_design_scores_gemma":[0.0007398361,0.0002684414,0.0001586402,0.00003538241,0.00008872164,0.00002186014,0.0003489848,0.000001484483,0.9979787,0.0002522286,0.0000288719,0.00007684118],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9995615,0.0001700588,7.742094e-7,0.00003596726,0.00005848456,0.00007734453,0.00001363155,0.000004332023,0.0000778619],"genre_scores_gemma":[0.9996361,0.00001130809,0.00003117165,0.00001765991,0.0002351859,0.000001187221,5.527525e-7,0.000009325017,0.00005757815],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002318145,"threshold_uncertainty_score":0.305346,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006372497083009738,"score_gpt":0.2335914760473081,"score_spread":0.2272189789642983,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}