{"id":"W2321969768","doi":"10.1021/jp408666q","title":"Pressure-Induced Changes on The Electronic Structure and Electron Topology in the Direct FCC → SH Transformation of Silicon","year":2013,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry C","topic":"Semiconductor materials and interfaces","field":"Physics and Astronomy","cited_by":25,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa; University of Saskatchewan","funders":"European Synchrotron Radiation Facility","keywords":"Silicon; Atomic orbital; Valence electron; Valence (chemistry); Molecular physics; Atom (system on chip); Hydrostatic pressure; Core electron; Electron; Materials science; Raman spectroscopy; Crystallography; Chemistry; Atomic physics; Physics; Optics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00004194105,0.0001143156,0.0001048695,0.0001803627,0.0002466539,0.000240219,0.0001848868,0.0001653883,0.002714596],"category_scores_gemma":[0.0002479586,0.0001551403,0.00006267397,0.0002239643,0.0004973315,0.0001680365,0.0001858924,0.0002347098,0.0001254377],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002911252,"about_ca_system_score_gemma":0.0001673925,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002315545,"about_ca_topic_score_gemma":0.002961006,"domain_scores_codex":[0.9999275,0.000003571713,0.00000288002,0.000009055252,0.0000349535,0.00002205306],"domain_scores_gemma":[0.9999377,0.00002201382,0.00001098217,0.000008095589,0.00001305059,0.000008283794],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004965175,0.0000336011,0.004528431,0.0001025409,0.00001732667,0.0006723355,0.0003320965,0.001775193,0.9834204,0.001362213,0.0004236622,0.006835732],"study_design_scores_gemma":[0.00003337447,0.0003142481,0.05777596,0.000008471033,0.00001084927,0.0004965187,0.0005116501,0.007554789,0.9310549,0.0005826061,0.00163841,0.00001814367],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9988666,0.00003890815,0.00008309024,0.00001659358,0.000001931891,0.000002008665,0.00006520465,0.00001050294,0.0009153127],"genre_scores_gemma":[0.9996517,0.00002466741,0.0000424151,0.00000400666,0.000001059824,0.000002145065,0.00006958681,0.000003526126,0.0002009742],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002714596,"threshold_uncertainty_score":0.009081244,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007961548127930063,"score_gpt":0.2417225791819457,"score_spread":0.2337610310540156,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}