{"id":"W2321972836","doi":"10.1021/ol500267w","title":"Improved Zinc-Catalyzed Simmons–Smith Reaction: Access to Various 1,2,3-Trisubstituted Cyclopropanes","year":2014,"lang":"en","type":"article","venue":"Organic Letters","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":65,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal; Centre in Green Chemistry and Catalysis","funders":"","keywords":"Chemistry; Catalysis; Zinc; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001890088,0.0004701132,0.0004553863,0.0001791146,0.0002780165,0.0002627302,0.0008472678,0.0002294856,0.0009024708],"category_scores_gemma":[0.0002736979,0.0004718444,0.0001431028,0.0005790927,0.00006249887,0.0004808308,0.0002757134,0.0004896239,0.0007948123],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003909423,"about_ca_system_score_gemma":0.0001176818,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000297234,"about_ca_topic_score_gemma":0.00008409416,"domain_scores_codex":[0.9974495,0.00004249726,0.0005019037,0.0008910698,0.0004514191,0.0006636531],"domain_scores_gemma":[0.9979929,0.0001074843,0.0002642749,0.001163022,0.0001244358,0.0003479011],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008154591,0.00006390749,0.0001394708,0.0001146138,0.00006798396,0.00002669249,0.0002421909,0.000009224758,0.9891193,0.00004911591,0.001307657,0.008778316],"study_design_scores_gemma":[0.001117132,0.00002366378,0.0004912271,0.00005291088,0.0001040861,0.000144367,0.0001183404,0.0001265782,0.9369129,0.00002346892,0.06024593,0.000639416],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9780183,0.00004127267,0.01166267,0.005149797,0.0008598332,0.0003484218,0.00001403701,0.0009280751,0.002977621],"genre_scores_gemma":[0.9945029,0.00001961246,0.001564017,0.002300894,0.0009155479,0.00009077813,0.00009355403,0.0001549101,0.0003578012],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05893828,"threshold_uncertainty_score":0.9999832,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009968390813787958,"score_gpt":0.2290800479959933,"score_spread":0.2191116571822053,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}