{"id":"W2322126741","doi":"10.1021/ac101980k","title":"Temperature Difference between the Cooled and the Noncooled Parts of an Electrolyte in Capillary Electrophoresis","year":2010,"lang":"en","type":"article","venue":"Analytical Chemistry","topic":"Microfluidic and Capillary Electrophoresis Applications","field":"Engineering","cited_by":32,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"Natural Sciences and Engineering Research Council of Canada; York University","keywords":"Capillary electrophoresis; Chemistry; Capillary action; Joule heating; Electrolyte; Inlet; Analytical Chemistry (journal); Chromatography; Thermal conduction; Electrophoresis; Joule–Thomson effect; Conductivity; Thermodynamics; Electrode; Composite material; Materials science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001830924,0.0007543489,0.001140028,0.0004207455,0.0007470199,0.001403331,0.001175149,0.00124983,0.0006020149],"category_scores_gemma":[0.0037145,0.0008654502,0.0003746015,0.0006825344,0.001540609,0.001524701,0.0006414445,0.001715034,0.0005765815],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006411285,"about_ca_system_score_gemma":0.0006904099,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005319942,"about_ca_topic_score_gemma":0.001103082,"domain_scores_codex":[0.9981487,0.0004261832,0.0001006346,0.0006195538,0.000579261,0.0001257169],"domain_scores_gemma":[0.9978941,0.001105804,0.0003612053,0.0002203824,0.0003103746,0.0001082501],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001003822,0.00001881923,0.0003109333,0.0001737606,0.00001181424,0.00007232598,0.00009891014,0.0002177562,0.9935184,0.0002952816,0.00006469918,0.00511676],"study_design_scores_gemma":[0.000008299475,0.0001398975,0.001104947,0.00001449514,0.00002675644,0.0002447849,0.00002134283,0.001401494,0.9956566,0.0002164362,0.001135966,0.0000289576],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7224535,0.02426821,0.2483158,0.0005887752,0.0006917179,0.0003189463,0.0002688826,0.0006350618,0.002459089],"genre_scores_gemma":[0.8229665,0.006413943,0.1667144,0.0002556181,0.0001198357,0.0003138006,0.0002322126,0.0001824094,0.002801169],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001830924,"threshold_uncertainty_score":0.009682953,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.002977178989269409,"score_gpt":0.1950979809997782,"score_spread":0.1921208020105088,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}