{"id":"W2322408572","doi":"10.1021/om500775c","title":"Carbon–Carbon Bond Forming Reactions with Tantalum Diamidophosphine Complexes That Incorporate Alkyne Ligands","year":2014,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Alkyne; Chemistry; Moiety; Hydride; Triple bond; Derivative (finance); Context (archaeology); Nuclear magnetic resonance spectroscopy; Phenylacetylene; Tantalum; Crystallography; Stereochemistry; Polymer chemistry; Double bond; Organic chemistry; Catalysis; Metal","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003763826,0.0006280645,0.0008894237,0.0002387432,0.0003088773,0.0001880737,0.0006067148,0.0002063532,0.005107218],"category_scores_gemma":[0.00012349,0.0005376914,0.0002303928,0.0009936733,0.0002648094,0.0002426204,0.0002550373,0.0003988943,0.00004437385],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001745895,"about_ca_system_score_gemma":0.00008583614,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003741273,"about_ca_topic_score_gemma":0.0003308323,"domain_scores_codex":[0.9971428,0.00002124301,0.0006305696,0.0008362136,0.0006640956,0.0007050894],"domain_scores_gemma":[0.9974653,0.0002186153,0.0005285085,0.001315153,0.0001398847,0.0003325694],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009826248,0.0005365442,0.02326686,0.0003249079,0.0007765112,0.00003532664,0.000354828,0.00003297395,0.9578317,0.003357814,0.00003401963,0.01335021],"study_design_scores_gemma":[0.001628185,0.0001910843,0.007365501,0.0001830413,0.0009262605,0.0001614391,0.0008002361,0.003133672,0.8840326,0.002131997,0.09761426,0.00183173],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9204147,0.0003236083,0.0001168708,0.0003711348,0.0001117389,0.0001212476,0.00004052254,0.0003207044,0.07817949],"genre_scores_gemma":[0.9899072,0.0001408992,0.0007358977,0.00008491689,0.0003533834,0.00004782285,0.0001976293,0.0001773648,0.008354883],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.09758024,"threshold_uncertainty_score":0.9997075,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01325575879133661,"score_gpt":0.1989926240366989,"score_spread":0.1857368652453623,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}