{"id":"W2322416032","doi":"10.1149/1.3013284","title":"Towards Molecular-Level Understanding of Electrocatalytic Hydrogenation. A Comparison of Cyclic Voltammetric Behavior of Benzene Adsorption at Pt(111) Single Crystal Electrodes in Aqueous HClO4 and H2SO4","year":2008,"lang":"en","type":"article","venue":"ECS Transactions","topic":"Electrochemical Analysis and Applications","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke; Queen's University","funders":"Natural Sciences and Engineering Research Council of Canada; Universidad de la República Uruguay; Fonds Québécois de la Recherche sur la Nature et les Technologies","keywords":"Overlayer; Adsorption; Cyclic voltammetry; Monolayer; Perchlorate; Aqueous solution; Chemistry; Inorganic chemistry; Benzene; Electrochemistry; Underpotential deposition; Perchloric acid; Electrode; Ion; Physical chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002033159,0.000345989,0.0003693101,0.0002880704,0.0001277282,0.0004052238,0.000574509,0.000736728,0.002079402],"category_scores_gemma":[0.0003799532,0.0002368519,0.0002654268,0.0002069208,0.0004931538,0.001014014,0.0002227829,0.0008217468,0.0004399559],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004732828,"about_ca_system_score_gemma":0.0001552615,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004669229,"about_ca_topic_score_gemma":0.0004096325,"domain_scores_codex":[0.9999142,0.0000126035,0.000004692618,0.00001615284,0.00003928504,0.0000130611],"domain_scores_gemma":[0.9999286,0.00003350325,0.00001092042,0.0000108243,0.00001061419,0.000005517725],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006954288,0.00005138178,0.0005800632,0.0004698236,0.00002220686,0.0000788224,0.00006120632,0.002703335,0.9819193,0.008514796,0.0001669969,0.005362561],"study_design_scores_gemma":[0.00001878698,0.000263689,0.005655655,0.00003319913,0.00003324967,0.0003229112,0.0001140926,0.08993801,0.888483,0.007342256,0.007769873,0.00002528995],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7746192,0.01385304,0.1962616,0.00148944,0.0001630758,0.0001131957,0.0008672596,0.001063011,0.01157016],"genre_scores_gemma":[0.9640194,0.00400739,0.02999151,0.000142127,0.00003265758,0.00005960166,0.0004574085,0.00002503495,0.001265037],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002079402,"threshold_uncertainty_score":0.006956279,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04496590889710213,"score_gpt":0.2645574989600036,"score_spread":0.2195915900629015,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}