{"id":"W2322652127","doi":"10.1021/ja404798q","title":"New Dihexadecyldithiophosphate SAMs on Gold Provide Insight into the Unusual Dependence of Adsorbate Chelation on Substrate Morphology in SAMs of Dialkyldithiophosphinic Acids","year":2013,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Molecular Junctions and Nanostructures","field":"Engineering","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"","keywords":"Chemistry; Monolayer; Denticity; Self-assembled monolayer; Alkyl; X-ray photoelectron spectroscopy; Chelation; Substrate (aquarium); Absorption spectroscopy; Crystallography; Chemical physics; Inorganic chemistry; Organic chemistry; Chemical engineering; Crystal structure","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008240383,0.0002537102,0.0001558717,0.0001320793,0.0001020959,0.0001934082,0.000178826,0.0002396245,0.0005657165],"category_scores_gemma":[0.0001533273,0.0001941106,0.0001387528,0.0001075873,0.0001709365,0.0002301948,0.0001740886,0.0002403968,0.0002076689],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001082129,"about_ca_system_score_gemma":0.00006474323,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001957178,"about_ca_topic_score_gemma":0.0004371679,"domain_scores_codex":[0.9999405,0.000005891723,0.000005926922,0.00001517907,0.00002066053,0.00001177109],"domain_scores_gemma":[0.9999225,0.00002169399,0.000018915,0.000008871853,0.0000112934,0.00001667898],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001207031,0.00000253242,0.0001482017,0.00001775429,0.000001952294,0.00004036872,0.00001280393,0.00004182893,0.9992834,0.00001470447,0.000005224851,0.0004194032],"study_design_scores_gemma":[0.000002640392,0.00003986739,0.001904888,0.000001229002,0.000004398902,0.0001158366,0.00001671409,0.0005641805,0.9970201,0.00002004807,0.0003078377,0.000002307929],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9972536,0.0002485021,0.001953216,0.00003108098,0.000006549332,0.000008712075,0.00008985699,0.00003890116,0.0003696276],"genre_scores_gemma":[0.9908658,0.0003612349,0.00756109,0.00002997014,0.000003770179,0.0000198822,0.0001916077,0.00001953387,0.0009471443],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0005657165,"threshold_uncertainty_score":0.001892507,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005902001639650524,"score_gpt":0.211233125011194,"score_spread":0.2053311233715435,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}