{"id":"W2322815344","doi":"10.1139/cjp-2012-0540","title":"Temperature-dependent reorientation dynamics of laser dyes in alkane and alcohol solvents","year":2013,"lang":"en","type":"article","venue":"Canadian Journal of Physics","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":19,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Alkane; Picosecond; Molecule; Relaxation (psychology); Alcohol; Coumarin; Fluorescence; Laser; Excitation; Rotational dynamics; Molecular physics; Photochemistry; Physics; Chemical physics; Chemistry; Hydrocarbon; Organic chemistry; Optics","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005205931,0.00009030201,0.0001715035,0.00003366052,0.00004111338,0.00002160863,0.00009662174,0.00005461254,0.00007103305],"category_scores_gemma":[0.00001783876,0.00008829174,0.00004180696,0.00007195387,0.00005893866,0.0001421283,0.000004701314,0.0002158931,9.770611e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001165401,"about_ca_system_score_gemma":0.0001936958,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002173458,"about_ca_topic_score_gemma":0.008027696,"domain_scores_codex":[0.9994048,0.000007308975,0.0002313703,0.00007736479,0.0001028101,0.0001763326],"domain_scores_gemma":[0.9995322,0.00001900584,0.00009252041,0.00007625986,0.000117365,0.0001626985],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000593967,0.0001238161,0.09426358,0.0004675022,0.000292011,0.0001023985,0.002990672,0.0003024949,0.8917118,0.0007376458,0.001083327,0.0078654],"study_design_scores_gemma":[0.0008839197,0.00004386422,0.004152828,0.0001622662,0.00003571677,0.00003178261,0.001038784,0.00008337074,0.9893063,0.004052525,0.00006230706,0.0001463571],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9985272,0.000217494,0.00001657295,0.0001617789,0.00004643014,0.00003554065,0.00003207489,0.000001546131,0.0009613984],"genre_scores_gemma":[0.9996355,0.00005031327,0.00003019509,0.00002751958,0.00007428748,0.000003573011,0.00001127342,0.00000813217,0.0001592009],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.09759453,"threshold_uncertainty_score":0.4479643,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00710960251238541,"score_gpt":0.2141857574263632,"score_spread":0.2070761549139778,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}