{"id":"W2322840544","doi":"10.1021/om200336t","title":"The Thioether–Methyleneborane (PhSCH<sub>2</sub>B(C<sub>6</sub>F<sub>5</sub>)<sub>2</sub>)<sub>2</sub>: Synthesis and Reactivity with Donors and Alkynes","year":2011,"lang":"en","type":"article","venue":"Organometallics","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":55,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Thioether; Thioanisole; Dimer; Yield (engineering); Reactivity (psychology); Adduct; Monomer; Crystallography; Stereochemistry; Nuclear magnetic resonance spectroscopy; Medicinal chemistry; Organic chemistry; Polymer; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","scholarly_communication","research_integrity"],"consensus_categories":["metaepi_narrow","sts","research_integrity"],"category_scores_codex":[0.002417094,0.003944388,0.00357959,0.0006709411,0.002292542,0.001271976,0.002659395,0.002939397,0.0002222824],"category_scores_gemma":[0.001851972,0.00353037,0.001055415,0.002562914,0.002996449,0.001807064,0.001686243,0.003801482,0.0006316407],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0009559251,"about_ca_system_score_gemma":0.00120304,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001537536,"about_ca_topic_score_gemma":0.001516923,"domain_scores_codex":[0.985131,0.0007667904,0.00283436,0.004714877,0.00258261,0.003970336],"domain_scores_gemma":[0.9869186,0.00267144,0.002288548,0.00478376,0.0009596947,0.002377945],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0009921951,0.001321786,0.005421115,0.001268941,0.001667589,0.0003292582,0.001657046,0.000007351663,0.916147,0.0001576025,0.0007418004,0.07028831],"study_design_scores_gemma":[0.003364765,0.0003538495,0.007422023,0.0006316428,0.001966748,0.0006543403,0.001785228,0.00008035444,0.9769676,0.0006227056,0.001862412,0.004288331],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9887628,0.003587537,0.00013399,0.001276666,0.0007537956,0.001372911,0.0007578118,0.001323371,0.002031138],"genre_scores_gemma":[0.9688421,0.02678225,0.0002762931,0.0007083277,0.001302746,0.0004326381,0.0002809145,0.001292561,0.00008213986],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.06599998,"threshold_uncertainty_score":0.9997648,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01263543290967946,"score_gpt":0.1963242560179783,"score_spread":0.1836888231082989,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}