{"id":"W2322853806","doi":"10.1021/om500911f","title":"Hydroalumination of Alkenes and Alkynes by Primary Aluminum Hydrides under Mild Conditions","year":2014,"lang":"en","type":"article","venue":"Organometallics","topic":"Coordination Chemistry and Organometallics","field":"Chemistry","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"Basic Energy Sciences; Natural Sciences and Engineering Research Council of Canada; U.S. Department of Energy","keywords":"Chemistry; Steric effects; Reactivity (psychology); Substituent; Moiety; Medicinal chemistry; Terphenyl; Monomer; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001788457,0.0004690404,0.0002110631,0.0001222077,0.0001345102,0.000135111,0.0002601949,0.0002006893,0.001286977],"category_scores_gemma":[0.0001879407,0.0001590368,0.000247701,0.0001144207,0.0001851082,0.0003521657,0.0003555306,0.0004486508,0.0004518715],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001982228,"about_ca_system_score_gemma":0.0002140306,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004357346,"about_ca_topic_score_gemma":0.001475897,"domain_scores_codex":[0.9998349,0.00002498312,0.00001087033,0.00002610673,0.00003542023,0.00006778369],"domain_scores_gemma":[0.9999168,0.00001351816,0.00002356265,0.0000147201,0.0000155736,0.00001569563],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009550653,0.0000183859,0.00008353689,0.0001258273,0.00001138037,0.0001441286,0.00008110143,0.0001680768,0.9966453,0.0002512595,0.00009834438,0.002277227],"study_design_scores_gemma":[0.00001247368,0.0002522997,0.0004824015,0.000005252663,0.000007211366,0.0001240707,0.00003043311,0.0001612359,0.9966271,0.00005328854,0.002238408,0.000005850489],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.988358,0.001440377,0.003188321,0.00007488416,0.00003694308,0.00005302896,0.0002062706,0.00007678143,0.006565527],"genre_scores_gemma":[0.9949391,0.0008221733,0.001506593,0.00003497264,0.000009950541,0.00001961581,0.0001621478,0.00001901922,0.00248631],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001286977,"threshold_uncertainty_score":0.004305363,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00706624757701955,"score_gpt":0.2132767519931881,"score_spread":0.2062105044161686,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}