{"id":"W2322858362","doi":"10.1021/jp309900n","title":"On the Interaction of Phosphines with High Surface Area Mesoporous Silica","year":2012,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry C","topic":"Mesoporous Materials and Catalysis","field":"Materials Science","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"","keywords":"Steric effects; Silanol; Phosphine; Catalysis; Reactivity (psychology); Chemistry; Mesoporous silica; Mesoporous material; Metal; Surface modification; Context (archaeology); Coordination sphere; Combinatorial chemistry; Chemical engineering; Organic chemistry; Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008876794,0.0002933354,0.0001695192,0.0001253894,0.000146689,0.0001581662,0.0002265722,0.0003082296,0.001337805],"category_scores_gemma":[0.0001497248,0.0001303167,0.0002732112,0.00008399123,0.0001464101,0.0001988264,0.0002086643,0.0002744445,0.0003223978],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001768497,"about_ca_system_score_gemma":0.00007610909,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005032101,"about_ca_topic_score_gemma":0.0008218634,"domain_scores_codex":[0.9998957,0.00001018644,0.000004860859,0.00002220057,0.00003235572,0.00003468919],"domain_scores_gemma":[0.9999543,0.00001902203,0.00001071678,0.00000404495,0.000005806393,0.000006065928],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005990505,0.00001287085,0.00009087484,0.00009842767,0.000009845878,0.00009749558,0.0000244452,0.0003175663,0.9979061,0.0002886964,0.00007950311,0.001014132],"study_design_scores_gemma":[0.000008782305,0.0002428384,0.001107272,0.0000075475,0.00001478983,0.00008511847,0.0000196511,0.003580522,0.9932349,0.00006346683,0.001625933,0.000009180337],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9922875,0.000881828,0.00277109,0.00008277077,0.00004228735,0.00002654586,0.0001096913,0.00006720616,0.003731145],"genre_scores_gemma":[0.996864,0.0004549901,0.001149113,0.00003467212,0.00001268986,0.00001054945,0.00008750668,0.00001147362,0.001374996],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001337805,"threshold_uncertainty_score":0.004475355,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01068894815833238,"score_gpt":0.229387092095317,"score_spread":0.2186981439369846,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}