{"id":"W2323141836","doi":"10.1021/ja410647c","title":"Intramolecular and Lateral Intermolecular Hole Transfer at the Sensitized TiO<sub>2</sub> Interface","year":2013,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Electrochemical Analysis and Applications","field":"Chemistry","cited_by":54,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Chemistry; Photochemistry; Intermolecular force; Excited state; Ruthenium; Ligand (biochemistry); Intramolecular force; Carboxylate; Electron transfer; Quantum yield; Crystallography; Stereochemistry; Molecule; Fluorescence; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008463459,0.0002929326,0.0001536959,0.00007886217,0.0001008927,0.0004018266,0.0002563628,0.0002973387,0.001049793],"category_scores_gemma":[0.0001944175,0.0001262798,0.0001442348,0.00007138238,0.0001890574,0.0003106454,0.0001434596,0.0002852268,0.0002751854],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002150995,"about_ca_system_score_gemma":0.00008501218,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003933441,"about_ca_topic_score_gemma":0.0004592842,"domain_scores_codex":[0.9999056,0.000009783792,0.000004980862,0.00002262506,0.00003331628,0.00002358822],"domain_scores_gemma":[0.9999201,0.00002754649,0.00001840107,0.000008424712,0.00001553694,0.000009999099],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001985884,0.000004026036,0.0001096561,0.00001099878,0.000002051908,0.00001582145,0.000005677924,0.00002497019,0.9992319,0.00002417961,0.000006493985,0.0005442488],"study_design_scores_gemma":[0.000003789196,0.0000805859,0.002914934,0.000001383808,0.000008621279,0.00008613616,0.00001623538,0.0008515412,0.9956377,0.00002586905,0.0003708562,0.000002255151],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9946294,0.0006065658,0.002993744,0.00003137881,0.00001077404,0.00001430232,0.00009018504,0.00007788388,0.001545724],"genre_scores_gemma":[0.9981719,0.0001423573,0.0008762631,0.00002108963,0.000004072802,0.00001179609,0.00005675691,0.00001124189,0.000704531],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001049793,"threshold_uncertainty_score":0.003511906,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003140543288717863,"score_gpt":0.2038099834711604,"score_spread":0.2006694401824426,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}