{"id":"W2323159062","doi":"10.1021/om400079b","title":"Oxidation of a Dimethylplatinum(II) Complex with Oxaziridines: A Hemiaminal Intermediate but No Oxo Complex","year":2013,"lang":"en","type":"article","venue":"Organometallics","topic":"Organic Chemistry Cycloaddition Reactions","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Hemiaminal; Medicinal chemistry; Oxaziridine; Imine; Methanol; Platinum; Molecule; Enamine; Stereochemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00007014473,0.0003616599,0.0004687896,0.00009515507,0.0001674658,0.00006360071,0.0003986474,0.0001708567,0.07648827],"category_scores_gemma":[0.0001930206,0.0003345383,0.000121582,0.000449143,0.000303093,0.0003105774,0.0001862964,0.0002989675,0.0006639495],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001651931,"about_ca_system_score_gemma":0.0001115502,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001018685,"about_ca_topic_score_gemma":0.0000143421,"domain_scores_codex":[0.9981288,0.00001665162,0.0005990913,0.0004460963,0.0004374603,0.0003719123],"domain_scores_gemma":[0.9980398,0.0001499275,0.0004869155,0.0006694924,0.0004441875,0.0002097189],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000252175,0.0002810538,0.0006851081,0.0001991273,0.0001330186,0.000003581611,0.0001327379,0.000002899304,0.9937378,0.00004708336,0.003969216,0.000783154],"study_design_scores_gemma":[0.001249177,0.00009286038,0.007306186,0.00008030387,0.000125363,0.0000927336,0.0005897153,0.0004610146,0.9652254,0.00009919942,0.02416462,0.0005134484],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9734409,0.00001226986,0.0003545204,0.0002685537,0.00005331886,0.0001665988,0.000232521,0.0001810055,0.02529027],"genre_scores_gemma":[0.9876861,0.00001955001,0.00379856,0.00008760015,0.0002489349,0.00005963576,0.001345587,0.00007611328,0.006677931],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.07582432,"threshold_uncertainty_score":0.9999107,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01523191128244307,"score_gpt":0.2174921978299552,"score_spread":0.2022602865475121,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}