{"id":"W2323194623","doi":"10.1021/ic201895y","title":"Ligand-Triplet-Fueled Long-Lived Charge Separation in Ruthenium(II) Complexes with Bithienyl-Functionalized Ligands","year":2011,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":30,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Ruthenium; Ligand (biochemistry); Charge (physics); Photochemistry; Catalysis; Organic chemistry; Receptor","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002490424,0.0003030383,0.0005462512,0.00007841471,0.0001475441,0.00002697397,0.0001731348,0.0001712558,0.005665677],"category_scores_gemma":[0.0001068151,0.0002259972,0.0001013632,0.0003687266,0.0001306564,0.0001118735,0.0000775586,0.0003093535,0.0001152586],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009173732,"about_ca_system_score_gemma":0.0001744227,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001089867,"about_ca_topic_score_gemma":0.00002905407,"domain_scores_codex":[0.9983621,0.00002680568,0.0004708923,0.0004345936,0.0003643279,0.000341303],"domain_scores_gemma":[0.9990334,0.00004713006,0.0001646963,0.0004547666,0.0001497125,0.0001502936],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001264459,0.0003408436,0.01637031,0.0002132786,0.0001089794,0.00002768406,0.001390372,2.94746e-7,0.9797903,0.00003567299,0.000329437,0.0001284084],"study_design_scores_gemma":[0.002558688,0.0002378665,0.0210249,0.0002153789,0.0001128322,0.0002002168,0.0001773226,0.00006502117,0.9733971,0.00009671181,0.001608952,0.0003049598],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9827232,0.0007461642,0.00005362625,0.0001941277,0.0000684284,0.0002917338,0.000009347581,0.0001176694,0.01579574],"genre_scores_gemma":[0.9897615,0.00005823352,0.000266046,0.000229881,0.0001939136,0.00004452046,0.00009394004,0.00004661018,0.009305354],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007038343,"threshold_uncertainty_score":0.9952433,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0492323219275384,"score_gpt":0.2578624081059854,"score_spread":0.208630086178447,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}