{"id":"W2323200187","doi":"10.1021/ic2003996","title":"Unsymmetrical 1λ<sup>3</sup>-1,2,4,6-Thiatriazinyls with Aryl and Trifluoromethyl Substituents: Synthesis, Crystal Structures, EPR Spectroscopy, and Voltammetry","year":2011,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Organic and Molecular Conductors Research","field":"Materials Science","cited_by":27,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Lethbridge","funders":"Natural Sciences and Engineering Research Council of Canada; Western Canada Research Grid; University of Lethbridge","keywords":"Chemistry; Electron paramagnetic resonance; Radical; Trifluoromethyl; Aryl; Cyclic voltammetry; Dimer; Crystallography; Ferrocene; Electrochemistry; Medicinal chemistry; Photochemistry; Physical chemistry; Organic chemistry; Nuclear magnetic resonance; Electrode","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001448792,0.0002640782,0.0001852028,0.0001213283,0.0001454527,0.0001645673,0.0004411751,0.0002627887,0.002072429],"category_scores_gemma":[0.0001537463,0.00015133,0.0001218865,0.0001976539,0.0002231579,0.0002106746,0.0001657337,0.0005183035,0.0005496911],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00026758,"about_ca_system_score_gemma":0.0002279435,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003674867,"about_ca_topic_score_gemma":0.0009567801,"domain_scores_codex":[0.9999226,0.000009964264,0.000006419611,0.00001892714,0.0000233054,0.0000186732],"domain_scores_gemma":[0.9998595,0.00001600884,0.00006782719,0.0000153403,0.00002301943,0.00001838836],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006258715,0.00001075632,0.00007739928,0.0001205826,0.000005232432,0.00005989172,0.0000414264,0.0001007803,0.996123,0.0004286572,0.0001401409,0.002829538],"study_design_scores_gemma":[0.0000303207,0.0004531992,0.001358544,0.000006377872,0.00001395874,0.0004181371,0.00003481614,0.000538498,0.988524,0.0001043037,0.008506229,0.00001168645],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9814138,0.003147044,0.009694587,0.0001791766,0.00008789888,0.00009270187,0.0004881206,0.0001922028,0.004704556],"genre_scores_gemma":[0.9729217,0.002700943,0.01540835,0.0001065261,0.00003193266,0.0001475722,0.0005824986,0.00005215168,0.008048388],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002072429,"threshold_uncertainty_score":0.006932974,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01492003948965155,"score_gpt":0.2219873004101853,"score_spread":0.2070672609205338,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}