{"id":"W2323200187","doi":"10.1021/ic2003996","title":"Unsymmetrical 1λ<sup>3</sup>-1,2,4,6-Thiatriazinyls with Aryl and Trifluoromethyl Substituents: Synthesis, Crystal Structures, EPR Spectroscopy, and Voltammetry","year":2011,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Organic and Molecular Conductors Research","field":"Materials Science","cited_by":27,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Lethbridge","funders":"Natural Sciences and Engineering Research Council of Canada; Western Canada Research Grid; University of Lethbridge","keywords":"Chemistry; Electron paramagnetic resonance; Radical; Trifluoromethyl; Aryl; Cyclic voltammetry; Dimer; Crystallography; Ferrocene; Electrochemistry; Medicinal chemistry; Photochemistry; Physical chemistry; Organic chemistry; Nuclear magnetic resonance; Electrode","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004359228,0.0004143148,0.0004922682,0.00009899004,0.0002188326,0.000173059,0.0004843214,0.0003135157,0.00313844],"category_scores_gemma":[0.0004825306,0.0003437793,0.00005769155,0.0006035133,0.0005031506,0.0002220215,0.0003535768,0.0004795006,0.00003818587],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001237705,"about_ca_system_score_gemma":0.000299575,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002266004,"about_ca_topic_score_gemma":0.000006837121,"domain_scores_codex":[0.9972839,0.00006520909,0.000402359,0.0009161457,0.0006247979,0.0007076115],"domain_scores_gemma":[0.9984697,0.0001837402,0.000137319,0.00062543,0.0001088729,0.0004749338],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001580772,0.00008492074,0.004780339,0.0001891169,0.00006616667,0.0001422198,0.0002526374,1.924651e-7,0.9937563,0.00007483026,0.0002086462,0.0002865563],"study_design_scores_gemma":[0.0009214067,0.0000900241,0.002796906,0.00004826492,0.0001113604,0.0004784144,0.0006538538,0.00001459576,0.9940132,0.0002439032,0.0001937662,0.0004342461],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9955421,0.002686829,0.0003398456,0.00007574674,0.00006441632,0.0002277218,0.00006431947,0.0001164502,0.000882581],"genre_scores_gemma":[0.9959621,0.0002600058,0.003312977,0.00004379731,0.0001711019,0.00001342552,0.00001076503,0.00006730444,0.0001585333],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003100255,"threshold_uncertainty_score":0.9999014,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01492003948965155,"score_gpt":0.2219873004101853,"score_spread":0.2070672609205338,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}