{"id":"W2323214359","doi":"10.1021/ic403108z","title":"Analysis of the Bonding between Two M(μ-NAr<sup>#</sup>) Monomers in the Dimeric Metal(II) Imido Complexes {M(μ-NAr<sup>#</sup>)}<sub>2</sub> [M = Si, Ge, Sn, Pb; Ar<sup>#</sup> = C<sub>6</sub>H<sub>3</sub>-2,6-(C<sub>6</sub>H<sub>2</sub>-2,4,6-R<sub>3</sub>)<sub>2</sub>]. The Stabilizing Role Played by R = Me and iPr","year":2014,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Academic Computer Centre Cyfronet, AGH University of Science and Technology; Infrastruktura PL-Grid; Canada Research Chairs","keywords":"Chemistry; Crystallography; Dimer; van der Waals force; Valence (chemistry); Natural bond orbital; Protonation; Intramolecular force; Density functional theory; Stereochemistry; Computational chemistry; Molecule","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007312307,0.0002147886,0.0002285801,0.0001335879,0.0002671629,0.0001866401,0.0004548585,0.00022312,0.001652045],"category_scores_gemma":[0.0001784909,0.0001816788,0.0001524621,0.000112659,0.0002570591,0.0003055359,0.0001897333,0.0003253052,0.0001696993],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002753279,"about_ca_system_score_gemma":0.0002159982,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007219883,"about_ca_topic_score_gemma":0.0007582786,"domain_scores_codex":[0.9999677,0.000005699412,0.000001080718,0.000008858168,0.00001030693,0.000006479934],"domain_scores_gemma":[0.9999506,0.00001417169,0.00001224382,0.000006028868,0.000007196924,0.000009718578],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004202641,0.0002415736,0.005842878,0.000438929,0.00009335787,0.000500795,0.0006356307,0.1180093,0.8121268,0.03862274,0.0008779345,0.02218988],"study_design_scores_gemma":[0.0000459425,0.0004526202,0.008405074,0.00002304043,0.00005210492,0.0003097352,0.0003552107,0.7752225,0.205858,0.005416096,0.003814923,0.00004478435],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9826139,0.0002085405,0.01386311,0.00006691455,0.000009821671,0.00001292288,0.00007145674,0.00005894245,0.003094418],"genre_scores_gemma":[0.9945177,0.0001429375,0.004486157,0.00001259771,0.000001913589,0.00002176198,0.00008581785,0.00001700454,0.0007140907],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001652045,"threshold_uncertainty_score":0.005526602,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009548548099058723,"score_gpt":0.2089941573062538,"score_spread":0.1994456092071951,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}