{"id":"W2323262610","doi":"10.1021/la300036y","title":"Quaternary Ammonium Bromide Surfactant Adsorption on Low-Index Surfaces of Gold. 2. Au(100) and the Role of Crystallographic-Dependent Adsorption in the Formation of Anisotropic Nanoparticles","year":2012,"lang":"en","type":"article","venue":"Langmuir","topic":"Gold and Silver Nanoparticles Synthesis and Applications","field":"Materials Science","cited_by":49,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan","funders":"","keywords":"Adsorption; Bromide; Chemistry; Pulmonary surfactant; Counterion; Ammonium bromide; Inorganic chemistry; Halide; Cationic polymerization; Gibbs isotherm; Cyclic voltammetry; Electrochemistry; Ion; Electrode; Physical chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006354195,0.00008329311,0.0001800296,0.00004698562,0.00003506827,0.00001600412,0.0001602195,0.00003946952,0.0000293471],"category_scores_gemma":[0.00001938173,0.00004657182,0.00004805687,0.0001312496,0.0001565209,0.0001921415,0.00003100977,0.00004297097,0.000004564911],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001264482,"about_ca_system_score_gemma":0.000009254578,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008007339,"about_ca_topic_score_gemma":0.0001651246,"domain_scores_codex":[0.998963,0.0001944799,0.0003487855,0.00009570366,0.0002283445,0.0001696911],"domain_scores_gemma":[0.9993136,0.000189714,0.0002478916,0.0001909749,0.00003500797,0.00002279395],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001588616,0.0002146436,0.02844373,0.00003616521,0.000003643125,6.994511e-8,0.002506863,0.00009406956,0.9634734,0.004751011,0.000009654756,0.0003078849],"study_design_scores_gemma":[0.0003961021,0.00005394422,0.1724119,0.00004166008,0.00001620254,0.000001949541,0.001620093,0.000914808,0.8238037,0.0006451955,0.00004478455,0.00004972033],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.999146,0.0002653862,0.00001147333,0.0001587291,0.00002657415,0.0002286965,0.00005150627,0.00000881943,0.0001028128],"genre_scores_gemma":[0.999833,0.00005525653,0.00003125945,0.00001692137,0.00001837687,0.00002839651,0.000005976486,0.000004993871,0.000005791469],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1439682,"threshold_uncertainty_score":0.1899144,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01150192183186858,"score_gpt":0.2217311673617626,"score_spread":0.210229245529894,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}