{"id":"W2323320027","doi":"10.1021/jp3055558","title":"Competition of Silene/Silylene Chemistry with Free Radical Chain Reactions Using 1-Methylsilacyclobutane in the Hot-Wire Chemical Vapor Deposition Process","year":2012,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Catalytic Processes in Materials Science","field":"Materials Science","cited_by":27,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Silylene; Chemistry; Radical; Chemical vapor deposition; Photochemistry; Decomposition; Isomerization; Propyne; Chain reaction; Chemical decomposition; Reactive intermediate; Chemical reaction; Propene; Chemical engineering; Organic chemistry; Catalysis; Silicon","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003339263,0.0005931188,0.0005161596,0.0002703356,0.0002303162,0.0005180103,0.0004155427,0.000442079,0.002499952],"category_scores_gemma":[0.0003726675,0.0002826788,0.000330756,0.0001665022,0.0003378462,0.0005321342,0.0002693335,0.0004714091,0.0004613507],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004286301,"about_ca_system_score_gemma":0.0002490529,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005524728,"about_ca_topic_score_gemma":0.001074618,"domain_scores_codex":[0.9996604,0.00003926077,0.00001344379,0.0000816369,0.0001023722,0.0001028814],"domain_scores_gemma":[0.9996705,0.0001542245,0.0000829454,0.00001600353,0.00003689684,0.00003940021],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009889493,0.00001102578,0.0003043736,0.00007308283,0.000008822912,0.00007530571,0.00001989778,0.0001181025,0.9981204,0.0001371832,0.00001459346,0.001018322],"study_design_scores_gemma":[0.000007825748,0.0001014438,0.00105969,0.000002413994,0.000007927645,0.00005662924,0.00000801925,0.0006817725,0.997826,0.0000325883,0.0002125928,0.000003053842],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9957377,0.001283313,0.001327704,0.00003542693,0.00001325943,0.00002262675,0.00005382893,0.00003087037,0.001495272],"genre_scores_gemma":[0.9967346,0.0005855457,0.001542661,0.0000165548,0.00001035696,0.00001246748,0.00009028632,0.00001953592,0.0009879784],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002499952,"threshold_uncertainty_score":0.008363128,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01140488631551058,"score_gpt":0.2633415740806606,"score_spread":0.25193668776515,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}