{"id":"W2323320027","doi":"10.1021/jp3055558","title":"Competition of Silene/Silylene Chemistry with Free Radical Chain Reactions Using 1-Methylsilacyclobutane in the Hot-Wire Chemical Vapor Deposition Process","year":2012,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Catalytic Processes in Materials Science","field":"Materials Science","cited_by":27,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Silylene; Chemistry; Radical; Chemical vapor deposition; Photochemistry; Decomposition; Isomerization; Propyne; Chain reaction; Chemical decomposition; Reactive intermediate; Chemical reaction; Propene; Chemical engineering; Organic chemistry; Catalysis; Silicon","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001466419,0.0001981017,0.0003656466,0.00001887688,0.0001152742,0.00004422006,0.00107469,0.00008414645,0.00009506038],"category_scores_gemma":[0.0003605761,0.0001131704,0.00008447101,0.0003909846,0.0007047128,0.0004364639,0.000100513,0.0003983321,0.000002321022],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001300324,"about_ca_system_score_gemma":0.0001700924,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002134596,"about_ca_topic_score_gemma":4.279669e-7,"domain_scores_codex":[0.9979753,0.0001019105,0.0005415576,0.0001625992,0.0008589756,0.0003596393],"domain_scores_gemma":[0.9981424,0.0003697082,0.0007357788,0.0004338328,0.0001976666,0.0001206662],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002912894,0.0004679008,0.00001575535,0.0003687401,0.000008625467,0.000007611908,0.001025072,0.001419601,0.9963348,0.00002578378,0.00000700438,0.00002782726],"study_design_scores_gemma":[0.0004670532,0.00004498295,0.00007039917,0.0003449279,0.00009992828,0.001475358,0.000841981,0.00146032,0.9944175,0.0006283512,0.000007293944,0.0001419005],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9976246,0.0001034161,0.001566427,0.0002289896,0.00004367548,0.0001050706,0.00002293112,0.00001240249,0.0002924326],"genre_scores_gemma":[0.9986801,0.000006779834,0.0005077559,0.00003465207,0.0007386756,0.000006622947,0.000005035407,0.00001435232,0.00000604869],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001917284,"threshold_uncertainty_score":0.4614953,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01140488631551058,"score_gpt":0.2633415740806606,"score_spread":0.25193668776515,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}