{"id":"W2323424559","doi":"10.1021/om000231e","title":"Ruthenium Dihydride RuH<sub>2</sub>(PPh<sub>3</sub>)<sub>2</sub>((<i>R</i>,<i>R</i>)-cyclohexyldiamine) and Ruthenium Monohydride RuHCl(PPh<sub>3</sub>)<sub>2</sub>((<i>R</i>,<i>R</i>)-cyclohexyldiamine):  Active Catalyst and Catalyst Precursor for the Hydrogenation of Ketones and Imines","year":2000,"lang":"en","type":"article","venue":"Organometallics","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":133,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Ruthenium; Heterolysis; Chemistry; Hydride; Medicinal chemistry; Dihydrogen complex; Stereochemistry; Base (topology); Hydrogen; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001138943,0.000294434,0.0002710078,0.0001321639,0.00007578253,0.0002377162,0.0004043267,0.0003216833,0.001264333],"category_scores_gemma":[0.0001675059,0.0002609305,0.000104055,0.0001143555,0.0002354807,0.0003558711,0.0002497128,0.0003420467,0.0003735947],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003140563,"about_ca_system_score_gemma":0.0001287635,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003871597,"about_ca_topic_score_gemma":0.0007454545,"domain_scores_codex":[0.9998791,0.00001564911,0.000007193699,0.00002393954,0.00004138212,0.00003271838],"domain_scores_gemma":[0.9999322,0.00001311827,0.00001848457,0.00001029479,0.000006535297,0.00001934512],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009446857,0.0000122472,0.0001329086,0.00006586823,0.000006270268,0.00005393597,0.00001133846,0.0001063857,0.9978928,0.0002482328,0.00007717657,0.001298461],"study_design_scores_gemma":[0.00001100041,0.00006427336,0.0004724154,0.00000120302,0.00000462257,0.0001224411,0.000008208087,0.000366388,0.9980379,0.00002647519,0.0008829274,0.000002170238],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9854209,0.001801527,0.007473436,0.00007562317,0.000051125,0.00007309294,0.0002484549,0.0002251462,0.004630875],"genre_scores_gemma":[0.993848,0.0004394898,0.003519926,0.00001689209,0.000004983006,0.00002088426,0.000146697,0.00002116258,0.001981999],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001264333,"threshold_uncertainty_score":0.004229605,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007716500307232054,"score_gpt":0.2054182715164758,"score_spread":0.1977017712092438,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}