{"id":"W2323424559","doi":"10.1021/om000231e","title":"Ruthenium Dihydride RuH<sub>2</sub>(PPh<sub>3</sub>)<sub>2</sub>((<i>R</i>,<i>R</i>)-cyclohexyldiamine) and Ruthenium Monohydride RuHCl(PPh<sub>3</sub>)<sub>2</sub>((<i>R</i>,<i>R</i>)-cyclohexyldiamine):  Active Catalyst and Catalyst Precursor for the Hydrogenation of Ketones and Imines","year":2000,"lang":"en","type":"article","venue":"Organometallics","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":133,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Ruthenium; Heterolysis; Chemistry; Hydride; Medicinal chemistry; Dihydrogen complex; Stereochemistry; Base (topology); Hydrogen; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","scholarly_communication","research_integrity"],"consensus_categories":["metaepi_narrow"],"category_scores_codex":[0.002318505,0.004103892,0.004373488,0.002418223,0.002240462,0.001121832,0.002497113,0.002190389,0.00008656159],"category_scores_gemma":[0.001617853,0.003928229,0.001831167,0.005699877,0.002574474,0.002741693,0.001422331,0.002140285,0.0002464246],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0009560533,"about_ca_system_score_gemma":0.0007861335,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002195869,"about_ca_topic_score_gemma":0.0009415502,"domain_scores_codex":[0.9828496,0.000599117,0.004651821,0.00501935,0.003211503,0.003668601],"domain_scores_gemma":[0.9856635,0.003419956,0.00336107,0.00385937,0.001544218,0.002151863],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001077793,0.001327774,0.001039695,0.001255188,0.003037464,0.00008575124,0.002985981,0.0003521044,0.9074016,0.0001337605,0.001015981,0.08028693],"study_design_scores_gemma":[0.006342112,0.0004210589,0.001941716,0.0003893761,0.00464514,0.0005875724,0.001587148,0.002654691,0.9716231,0.0006708079,0.005032173,0.004105132],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9796613,0.008321185,0.0008503728,0.001349937,0.0007557993,0.003510489,0.003774791,0.0008428311,0.0009332577],"genre_scores_gemma":[0.9674646,0.02285219,0.0002480244,0.0007847978,0.001519449,0.001525925,0.004274435,0.001089545,0.0002409947],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0761818,"threshold_uncertainty_score":0.9999151,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007716500307232054,"score_gpt":0.2054182715164758,"score_spread":0.1977017712092438,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}