{"id":"W2323426058","doi":"10.1021/ic3025793","title":"Reactions of a Cyclodimethylsiloxane (Me<sub>2</sub>SiO)<sub>6</sub>with Silver Salts of Weakly Coordinating Anions; Crystal Structures of [Ag(Me<sub>2</sub>SiO)<sub>6</sub>][Al] ([Al] = [FAl{OC(CF<sub>3</sub>)<sub>3</sub>}<sub>3</sub>], [Al{OC(CF<sub>3</sub>)<sub>3</sub>}<sub>4</sub>]) and Their Comparison with [Ag(18-Crown-6)]<sub>2</sub>[SbF<sub>6</sub>]<sub>2</sub>","year":2013,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":39,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of New Brunswick; Dalhousie University","funders":"CSC – IT Center for Science","keywords":"Chemistry; Crystallography; Crystal structure; Gas phase; Metal; Salt (chemistry); Lewis acids and bases; Crown ether; X-ray crystallography; 18-Crown-6; Stereochemistry; Molecule; Ion; Physical chemistry; Diffraction; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007694824,0.0002842726,0.000148738,0.00008383488,0.0001162328,0.0001348749,0.0002281157,0.000223489,0.001837613],"category_scores_gemma":[0.0001285281,0.0001453823,0.00017445,0.000112425,0.0001283773,0.0001379711,0.0001402645,0.0002613179,0.0006056649],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001557648,"about_ca_system_score_gemma":0.000175702,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006025723,"about_ca_topic_score_gemma":0.001577488,"domain_scores_codex":[0.9999218,0.000008220797,0.000007679935,0.00002348783,0.00002425263,0.00001463898],"domain_scores_gemma":[0.9999145,0.00001383069,0.00003260556,0.00001021204,0.00001353332,0.00001518742],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001331117,0.000009787259,0.0001497269,0.00008848265,0.00000819401,0.00004836769,0.00001922934,0.00007396401,0.9983672,0.000078343,0.00004211116,0.0009815376],"study_design_scores_gemma":[0.0000107838,0.000132778,0.0005575977,0.000001947137,0.000006732898,0.0000664676,0.00000831731,0.000128524,0.997137,0.00001461199,0.001932194,0.000002947611],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9919321,0.0008375958,0.003200886,0.00004755584,0.00005842311,0.00007396721,0.0004906735,0.0001088778,0.003249863],"genre_scores_gemma":[0.9897076,0.0007429165,0.005200412,0.00004438009,0.00001306356,0.00004960933,0.0004352354,0.00002870631,0.003778082],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001837613,"threshold_uncertainty_score":0.006147444,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00686366811240779,"score_gpt":0.2055831233554277,"score_spread":0.1987194552430199,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}