{"id":"W2323449200","doi":"10.1515/mgmc.2004.27.2.91","title":"Studies in Aryltin Chemistry. Part 15. The Sulphur Effect in the EI and Positive-ion FAB Mass-spectra of Some p-Methylthiophenyltin Compounds","year":2004,"lang":"en","type":"article","venue":"Main Group Metal Chemistry","topic":"Organometallic Compounds Synthesis and Characterization","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Brock University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Mass spectrum; Ion; Sulfur; Spectral line; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006619131,0.0006573942,0.0003464743,0.000618418,0.0007272447,0.0002559129,0.0004820778,0.0005089859,0.007403939],"category_scores_gemma":[0.0003946522,0.0002110371,0.0003637849,0.0005642298,0.0004745905,0.000427078,0.0003623371,0.000630662,0.0008085311],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005059977,"about_ca_system_score_gemma":0.0003547157,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001438968,"about_ca_topic_score_gemma":0.001295073,"domain_scores_codex":[0.9996669,0.00005818051,0.0000143426,0.00004139354,0.0001666168,0.00005266407],"domain_scores_gemma":[0.999727,0.0000613216,0.00005262445,0.00002575827,0.00009483483,0.00003843128],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003485486,0.00003120634,0.0001556134,0.0001846987,0.00002250576,0.0003331249,0.0001041583,0.00007167755,0.9894042,0.0003747281,0.001047883,0.007921655],"study_design_scores_gemma":[0.00006502865,0.002184776,0.003494606,0.00001689826,0.00004175127,0.001455845,0.00005404232,0.0002363186,0.9686332,0.0003605808,0.02343474,0.00002214234],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8577858,0.03521067,0.03062611,0.001794662,0.001404672,0.0006373989,0.001641099,0.0007314878,0.07016811],"genre_scores_gemma":[0.8967099,0.02235994,0.01728748,0.0009816301,0.0004418565,0.0002519868,0.002382522,0.0001704198,0.05941431],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007403939,"threshold_uncertainty_score":0.02476865,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01391413624934727,"score_gpt":0.2394269305847377,"score_spread":0.2255127943353904,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}