{"id":"W2323500790","doi":"10.1021/jo501299j","title":"Metal-Free Reduction of Secondary and Tertiary <i>N</i>-Phenyl Amides by Tris(pentafluorophenyl)boron-Catalyzed Hydrosilylation","year":2014,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":89,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Hydrosilylation; Aryl; Chemistry; Nitro; Catalysis; Yield (engineering); Tris; Halide; Boron; Medicinal chemistry; Metal; Organic chemistry; Functional group; Alkyl; Materials science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001093107,0.0003833305,0.0001520474,0.0001209521,0.00012695,0.0001445944,0.0002656005,0.0001894316,0.001579915],"category_scores_gemma":[0.0000798433,0.0001500185,0.0001736289,0.00009434325,0.0001627946,0.000198845,0.0001751088,0.0003362946,0.0007001024],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002053829,"about_ca_system_score_gemma":0.0001868919,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006739701,"about_ca_topic_score_gemma":0.001442846,"domain_scores_codex":[0.9999111,0.000007623417,0.000006732198,0.00001746004,0.00002861898,0.00002853074],"domain_scores_gemma":[0.9999646,0.000004659995,0.000009745805,0.000003606932,0.000008327344,0.000009045076],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003155612,0.000005128698,0.0000233293,0.00003217053,0.000002254065,0.00003143983,0.000009464334,0.00004178099,0.998218,0.0001010987,0.00007120903,0.001432521],"study_design_scores_gemma":[0.00000335304,0.00003927081,0.0001673837,0.00000152606,0.000002735664,0.00005425355,0.000003962038,0.0001077623,0.9986726,0.00001712984,0.000927711,0.00000231175],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9521539,0.002262322,0.02531392,0.0001377812,0.00008212071,0.00006280976,0.0007381175,0.0005275588,0.01872159],"genre_scores_gemma":[0.9852,0.001125913,0.007605712,0.0000535096,0.00001330391,0.00002292523,0.0006379381,0.00007771914,0.005262925],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001579915,"threshold_uncertainty_score":0.005285323,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004403593815606108,"score_gpt":0.1948488915587041,"score_spread":0.1904452977430979,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}