{"id":"W2323643135","doi":"10.1021/ja501772m","title":"Chemoselective N-Heterocyclic Carbene-Catalyzed Cross-Benzoin Reactions: Importance of the Fused Ring in Triazolium Salts","year":2014,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":122,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Foundation for Innovation; University of Saskatchewan","keywords":"Chemistry; Benzoin; Benzaldehyde; Carbene; Catalysis; Umpolung; Organic chemistry; Benzil; Ring (chemistry); Polar effect","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004115502,0.0002963367,0.0007386616,0.00001656547,0.0001171562,0.00003401619,0.001284797,0.0001837482,0.0001138709],"category_scores_gemma":[0.0008764428,0.000195434,0.0009581338,0.0005693952,0.0007478296,0.0001215327,0.0003547051,0.001211358,0.000001286189],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007463734,"about_ca_system_score_gemma":0.0001243143,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000124141,"about_ca_topic_score_gemma":0.000007686185,"domain_scores_codex":[0.9974272,0.00005171751,0.001178399,0.0003245239,0.0006019933,0.0004161283],"domain_scores_gemma":[0.9961473,0.0004023727,0.00234382,0.0008193788,0.0001664154,0.0001206532],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000107248,0.0001472081,0.02778119,0.0000909029,0.0001347407,5.786091e-7,0.0002739562,0.00001304533,0.9706255,0.000004462763,0.000431655,0.0003894866],"study_design_scores_gemma":[0.001819354,0.00001328493,0.004706255,0.0001486072,0.00007693278,0.0001083368,0.0003760053,0.0001477893,0.9913512,0.0002574633,0.0007831828,0.0002115951],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9980075,0.0001305142,0.00001431841,0.0004571304,0.0002034333,0.00007036679,0.00001233438,0.00001941611,0.001084958],"genre_scores_gemma":[0.9986292,0.00008978931,0.0002248406,0.0002949883,0.0005497477,0.000005503518,0.000002388892,0.00004554756,0.0001580327],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02307494,"threshold_uncertainty_score":0.7969565,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007968726085295854,"score_gpt":0.2588955404566927,"score_spread":0.2509268143713968,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}