{"id":"W2323678816","doi":"10.1139/cjc-2013-0355","title":"Infrared spectroscopic characterization of hydrogen-bonded propylene oxide − ethanol and propylene oxide − 2-fluoroethanol complexes isolated in solid neon matrices","year":2013,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Molecular Spectroscopy and Structure","field":"Chemistry","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Neon; Propylene oxide; Hydrogen bond; Hydrogen; Infrared spectroscopy; Inorganic chemistry; Oxide; Enthalpy; Kinetic isotope effect; Acceptor; Proton; Physical chemistry; Analytical Chemistry (journal); Deuterium; Molecule; Organic chemistry; Argon; Ethylene oxide; Atomic physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001955874,0.0003952972,0.0002480221,0.0002262486,0.0001655767,0.0002012955,0.0004744333,0.0002288077,0.001188525],"category_scores_gemma":[0.0004010218,0.0001755021,0.0001278458,0.0002992541,0.0001852197,0.0001768232,0.0001900147,0.0002695704,0.0001497718],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001986166,"about_ca_system_score_gemma":0.00008836154,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006882364,"about_ca_topic_score_gemma":0.0008035026,"domain_scores_codex":[0.9998232,0.00002602703,0.00001021939,0.00003357718,0.00007055071,0.00003640516],"domain_scores_gemma":[0.999815,0.00006371048,0.00004345406,0.00001134142,0.00004315926,0.00002330858],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006029143,0.000007247535,0.000179709,0.00004199986,0.00000800692,0.00005039824,0.00004116155,0.00009189646,0.9989529,0.0000356758,0.00001906945,0.0005116908],"study_design_scores_gemma":[0.00001186076,0.0002129857,0.003734993,0.000007836678,0.00001762212,0.00008855548,0.00007032861,0.001083165,0.9940329,0.00002061374,0.0007126305,0.000006504044],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.997523,0.0003921684,0.001183388,0.00001576395,0.000004788817,0.00001070297,0.00008902927,0.00001675986,0.0007645009],"genre_scores_gemma":[0.9962382,0.0004291123,0.001688939,0.00001915824,0.00000293939,0.00002178292,0.0003813739,0.00003344217,0.001184818],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001188525,"threshold_uncertainty_score":0.003975987,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004896396654000676,"score_gpt":0.2074847593763187,"score_spread":0.202588362722318,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}