{"id":"W2323808512","doi":"10.1021/ma2027484","title":"Aryl Amidine and Tertiary Amine Switchable Surfactants and Their Application in the Emulsion Polymerization of Methyl Methacrylate","year":2012,"lang":"en","type":"article","venue":"Macromolecules","topic":"Advanced Polymer Synthesis and Characterization","field":"Chemistry","cited_by":120,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Amidine; Chemistry; Emulsion polymerization; Pulmonary surfactant; Polymer chemistry; Polymerization; Tertiary amine; Amine gas treating; Methyl methacrylate; Ammonium bicarbonate; Emulsion; Organic chemistry; Polymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001464366,0.0001415212,0.000167692,0.00004616772,0.00005602865,0.00001615126,0.00008864725,0.00006999406,0.00002006598],"category_scores_gemma":[0.00002517898,0.00009825871,0.00002111913,0.0001233302,0.00005576282,0.000178176,0.00004807537,0.000071267,8.145997e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000008398701,"about_ca_system_score_gemma":0.00000322343,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006312348,"about_ca_topic_score_gemma":0.000006863271,"domain_scores_codex":[0.9992943,0.00003475329,0.0002319492,0.0001654105,0.0000957525,0.0001778823],"domain_scores_gemma":[0.9994949,0.00010237,0.0001501579,0.0001974938,0.00001584199,0.0000392653],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001718488,0.00005918299,0.0325467,0.00005563701,0.000009465124,3.250144e-7,0.0009059657,0.000001383388,0.9147633,0.0001118529,6.206717e-7,0.0515284],"study_design_scores_gemma":[0.0001749124,0.000008202017,0.04469567,0.00003400746,0.00001500156,0.000009439364,0.0004448332,0.0007285963,0.953491,0.0001428684,0.0001456657,0.0001098487],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9926802,0.002884155,0.003944901,0.0001521102,0.00001708719,0.00008683946,0.00002908369,0.00001792387,0.0001877152],"genre_scores_gemma":[0.9991718,0.0004032081,0.0001938254,0.00006336807,0.00003651548,0.00002327711,0.00006448125,0.00001832915,0.0000252153],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05141855,"threshold_uncertainty_score":0.4006874,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007473694052391174,"score_gpt":0.2242668556106112,"score_spread":0.21679316155822,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}