{"id":"W2323878865","doi":"10.1021/om4011406","title":"A Dual-Emissive Phosphine–Borane Lewis Pair with a U-Shaped Linker: Impact of Methylation and Complexation on Fluoride Binding Affinity","year":2014,"lang":"en","type":"article","venue":"Organometallics","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":23,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Killam Trusts","keywords":"Chemistry; Borane; Fluoride; Phosphine; Phosphonium; Linker; Photochemistry; Frustrated Lewis pair; Fluorescence; Solvent; Phosphonium salt; Binding constant; Lewis acids and bases; Ion; Salt (chemistry); Inorganic chemistry; Polymer chemistry; Medicinal chemistry; Organic chemistry; Binding site; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002249294,0.0003263854,0.0003045622,0.0001087581,0.0001446757,0.0002793222,0.0003525084,0.0003718068,0.0008898028],"category_scores_gemma":[0.0002587901,0.0001921624,0.0001462334,0.0001103157,0.0001722852,0.0003473761,0.0002757246,0.0003127205,0.0003478807],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000215145,"about_ca_system_score_gemma":0.0001433382,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003308872,"about_ca_topic_score_gemma":0.000628692,"domain_scores_codex":[0.9998679,0.00002923232,0.00000905651,0.00003850828,0.00002503176,0.00003021334],"domain_scores_gemma":[0.9998969,0.00002480859,0.00002758536,0.00001101536,0.00001259608,0.00002706376],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001200721,0.00002015885,0.0000717717,0.00003685011,0.000004710255,0.00003624622,0.00001566555,0.00006881788,0.9984206,0.00007748567,0.00002094878,0.001106583],"study_design_scores_gemma":[0.00001624571,0.0002075991,0.0001869248,0.000001786204,0.000006544883,0.00007709739,0.000006738205,0.0004103917,0.9983894,0.000007896986,0.0006843755,0.000005170314],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9964765,0.0003776379,0.002194705,0.00004510176,0.000007952762,0.0000228538,0.00005377586,0.00005833775,0.0007632016],"genre_scores_gemma":[0.9934514,0.0002808419,0.004668605,0.00003932795,0.000005119818,0.00002500247,0.00009568059,0.00001894431,0.001415098],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008898028,"threshold_uncertainty_score":0.002976716,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01419351208746916,"score_gpt":0.2477670069351141,"score_spread":0.2335734948476449,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}