{"id":"W2324125525","doi":"10.1021/ja063030w","title":"New Insight into Reactions of Ni(S<sub>2</sub>C<sub>2</sub>(CF<sub>3</sub>)<sub>2</sub>)<sub>2</sub> with Simple Alkenes:  Alkene Adduct versus Dihydrodithiin Product Selectivity Is Controlled by [Ni(S<sub>2</sub>C<sub>2</sub>(CF<sub>3</sub>)<sub>2</sub>)<sub>2</sub>]<sup>-</sup> Anion","year":2006,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Organic and Molecular Conductors Research","field":"Materials Science","cited_by":79,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Alkene; Adduct; Ethylene; Ion; Selectivity; Nickel; Sulfur; Stereochemistry; Crystallography; Photochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","metaepi_broad","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","metaepi_broad","sts","research_integrity"],"category_scores_codex":[0.01208878,0.01122273,0.01526769,0.003509013,0.006537018,0.003591848,0.01119627,0.005592355,0.0001439401],"category_scores_gemma":[0.007643658,0.0105465,0.0103283,0.01697161,0.01041812,0.007544349,0.006079021,0.0157124,0.001387784],"about_ca_system_candidate":true,"about_ca_system_consensus":true,"about_ca_system_score_codex":0.01170114,"about_ca_system_score_gemma":0.0119117,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00145337,"about_ca_topic_score_gemma":0.001604544,"domain_scores_codex":[0.9364768,0.007699064,0.01402538,0.01240928,0.01564712,0.01374242],"domain_scores_gemma":[0.9521351,0.005534605,0.01619249,0.01047826,0.007698594,0.007960935],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.01088545,0.006581817,0.0009799771,0.001435594,0.005507768,0.0007461136,0.003599911,0.001951306,0.8582059,0.00009411489,0.08345938,0.02655272],"study_design_scores_gemma":[0.02585629,0.004991011,0.001771711,0.002181923,0.005462601,0.002421644,0.002805172,0.002381947,0.9368823,0.001478874,0.00314815,0.01061839],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9660509,0.004756308,0.002990845,0.005996882,0.005128614,0.01005935,0.002472942,0.002228818,0.0003153579],"genre_scores_gemma":[0.9643497,0.01546748,0.0012667,0.00349089,0.008995335,0.001531157,0.00164483,0.003190295,0.00006360738],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.08031123,"threshold_uncertainty_score":0.999583,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008800633365548335,"score_gpt":0.2358810565738144,"score_spread":0.227080423208266,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}