{"id":"W2324125525","doi":"10.1021/ja063030w","title":"New Insight into Reactions of Ni(S<sub>2</sub>C<sub>2</sub>(CF<sub>3</sub>)<sub>2</sub>)<sub>2</sub> with Simple Alkenes:  Alkene Adduct versus Dihydrodithiin Product Selectivity Is Controlled by [Ni(S<sub>2</sub>C<sub>2</sub>(CF<sub>3</sub>)<sub>2</sub>)<sub>2</sub>]<sup>-</sup> Anion","year":2006,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Organic and Molecular Conductors Research","field":"Materials Science","cited_by":79,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Alkene; Adduct; Ethylene; Ion; Selectivity; Nickel; Sulfur; Stereochemistry; Crystallography; Photochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000531208,0.0002488121,0.0001420701,0.00009220133,0.0001131418,0.0001927489,0.0002029935,0.0003174141,0.002117393],"category_scores_gemma":[0.00005933142,0.00009404343,0.00009237188,0.0001206108,0.0002120721,0.000316309,0.0001630732,0.0003438968,0.0002920659],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000202263,"about_ca_system_score_gemma":0.0001405513,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003795777,"about_ca_topic_score_gemma":0.001001152,"domain_scores_codex":[0.9999671,0.000003987824,0.000001996183,0.000007983002,0.00001194762,0.000006955956],"domain_scores_gemma":[0.9999763,0.000006242154,0.000004449892,0.000003934265,0.000004728399,0.000004420352],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009610231,0.0000116252,0.0002020186,0.00008571345,0.000003210763,0.00007433708,0.00004225606,0.0001001923,0.9968086,0.0005812253,0.00003649167,0.001958135],"study_design_scores_gemma":[0.000004916411,0.0001396303,0.001610392,0.000003139154,0.000007518154,0.0003263494,0.00005953447,0.0006888295,0.9933932,0.0002848874,0.003475627,0.000005903161],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9844087,0.002396594,0.005802205,0.0001821955,0.00001861484,0.0000151417,0.0001495078,0.0001429384,0.00688409],"genre_scores_gemma":[0.9940079,0.001092169,0.002460652,0.00004656538,0.000007410988,0.000006534126,0.0001173122,0.0000114487,0.002249813],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002117393,"threshold_uncertainty_score":0.007083416,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008800633365548335,"score_gpt":0.2358810565738144,"score_spread":0.227080423208266,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}