{"id":"W2324147639","doi":"10.1021/om060399l","title":"Reactions of (η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>)Ir(PMe<sub>3</sub>)(SH)<sub>2</sub>and (η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>)Ir(PMe<sub>3</sub>)(SH)(H) with Thionylaniline (PhNSO) to Give Novel Iridium S<sub>3</sub>O and S<sub>2</sub>O Complexes","year":2007,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal; McGill University; University of Toronto","funders":"","keywords":"Chemistry; Crystal structure; Crystallography; X-ray crystallography; Infrared spectroscopy; Stereochemistry; Infrared; Medicinal chemistry; Physics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","metaepi_broad","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","sts","research_integrity"],"category_scores_codex":[0.00942558,0.01492886,0.01598126,0.009231091,0.006841192,0.004154492,0.009476782,0.008034776,0.0008382731],"category_scores_gemma":[0.005135126,0.01614046,0.006930822,0.01806171,0.007860915,0.006669951,0.007552859,0.01079713,0.003400949],"about_ca_system_candidate":true,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00606479,"about_ca_system_score_gemma":0.004475536,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003999669,"about_ca_topic_score_gemma":0.004228988,"domain_scores_codex":[0.9386854,0.002515897,0.0158291,0.01643217,0.01167187,0.01486563],"domain_scores_gemma":[0.9527423,0.006914293,0.009806475,0.01428435,0.006201756,0.01005077],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.004065572,0.008144658,0.002306111,0.004066314,0.008585216,0.001248567,0.004753043,0.002509324,0.8990538,0.0009883216,0.006319724,0.05795933],"study_design_scores_gemma":[0.01433115,0.002454391,0.01124013,0.002993794,0.008692138,0.003403836,0.006046453,0.003794126,0.9201213,0.00129982,0.009644315,0.01597852],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9598795,0.00558108,0.005851439,0.002841705,0.002303161,0.008352473,0.008189465,0.004426293,0.002574888],"genre_scores_gemma":[0.9560406,0.01844194,0.001655072,0.002643539,0.006082985,0.002106742,0.007648923,0.005122432,0.0002578036],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04198081,"threshold_uncertainty_score":0.9986275,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01322820420054825,"score_gpt":0.2177217533908263,"score_spread":0.204493549190278,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}